Electrochemical Behaviour and Electronic Absorption of the Metal β- Diketonates Complexes

Mohammed A. Al-Anber

doi:doi:10.11648/j.ajpc.20130201.11

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Electrochemical Behaviour and Electronic Absorption of the Metal β- Diketonates Complexes

Mohammed A. Al-Anber

Published in American Journal of Physical Chemistry (Volume 2, Issue 1)

Published: 20 February 2013

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Abstract

The electrochemical properties of -diketonate complexes, such as [Co(tta)2(H2O)2], [Ni(tta)2(H2O)2], [Cu(tta)2] and [Zn(tta)2(H2O)2] (tta = deprotonated of 1-thenoyl-4,4,4-trifluoroacetone) have been studied using cyclic voltammetry (CV). Their redox behaviors including oxidation and/ or reduction process for both central atom and tta ligand have been discussed. The cyclic voltammogrammes display one irreversible oxidation peak in a positive potential region, where it appears in the area between + 1.30 and + 1.95 V based on the type of complex. In addition, two reduction peaks are appeared in the negative region potentials, at the region between – 1.06 to – 2.16 V. The irreversible oxidation potential peak of thienyl ring has shifted to the lower positive potential, while the reversibly redox potential peak of the fluorinated--diketone moiety shifts to the higher negative potential compared with non-coordinated H-tta ligand. The spectral properties, energy levels, and energy gap for the respective complexes have been verified with UV-Vis spectrophotometer.

Published in	American Journal of Physical Chemistry (Volume 2, Issue 1)
DOI	10.11648/j.ajpc.20130201.11
Page(s)	1-7
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2013. Published by Science Publishing Group

Keywords

Cyclic Voltammetry, -Diketones, Electronic Spectra, 1-Thenoyl-4,4,4-Trifluoroacetone, Metal, Complex

References

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Mohammed A. Al-Anber. (2013). Electrochemical Behaviour and Electronic Absorption of the Metal β- Diketonates Complexes. American Journal of Physical Chemistry, 2(1), 1-7. https://doi.org/10.11648/j.ajpc.20130201.11

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ACS Style

Mohammed A. Al-Anber. Electrochemical Behaviour and Electronic Absorption of the Metal β- Diketonates Complexes. Am. J. Phys. Chem. 2013, 2(1), 1-7. doi: 10.11648/j.ajpc.20130201.11

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AMA Style

Mohammed A. Al-Anber. Electrochemical Behaviour and Electronic Absorption of the Metal β- Diketonates Complexes. Am J Phys Chem. 2013;2(1):1-7. doi: 10.11648/j.ajpc.20130201.11

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@article{10.11648/j.ajpc.20130201.11,
  author = {Mohammed A. Al-Anber},
  title = {Electrochemical Behaviour and Electronic Absorption of the Metal β- Diketonates Complexes},
  journal = {American Journal of Physical Chemistry},
  volume = {2},
  number = {1},
  pages = {1-7},
  doi = {10.11648/j.ajpc.20130201.11},
  url = {https://doi.org/10.11648/j.ajpc.20130201.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpc.20130201.11},
  abstract = {The electrochemical properties of -diketonate complexes, such as [Co(tta)2(H2O)2], [Ni(tta)2(H2O)2], [Cu(tta)2] and [Zn(tta)2(H2O)2] (tta = deprotonated of  1-thenoyl-4,4,4-trifluoroacetone) have been studied using cyclic voltammetry (CV). Their redox behaviors including oxidation and/ or reduction process for both central atom and tta ligand have been discussed. The cyclic voltammogrammes display one irreversible oxidation peak in a positive potential region, where it appears in the area between + 1.30 and + 1.95 V based on the type of complex. In addition, two reduction peaks are appeared in the negative region potentials, at the region between – 1.06 to – 2.16 V. The irreversible oxidation potential peak of thienyl ring has shifted to the lower positive potential, while the reversibly redox potential peak of the fluorinated--diketone moiety shifts to the higher negative potential compared with non-coordinated H-tta ligand. The spectral properties, energy levels, and energy gap for the respective complexes have been verified with UV-Vis spectrophotometer.},
 year = {2013}
}

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TY  - JOUR
T1  - Electrochemical Behaviour and Electronic Absorption of the Metal β- Diketonates Complexes
AU  - Mohammed A. Al-Anber
Y1  - 2013/02/20
PY  - 2013
N1  - https://doi.org/10.11648/j.ajpc.20130201.11
DO  - 10.11648/j.ajpc.20130201.11
T2  - American Journal of Physical Chemistry
JF  - American Journal of Physical Chemistry
JO  - American Journal of Physical Chemistry
SP  - 1
EP  - 7
PB  - Science Publishing Group
SN  - 2327-2449
UR  - https://doi.org/10.11648/j.ajpc.20130201.11
AB  - The electrochemical properties of -diketonate complexes, such as [Co(tta)2(H2O)2], [Ni(tta)2(H2O)2], [Cu(tta)2] and [Zn(tta)2(H2O)2] (tta = deprotonated of  1-thenoyl-4,4,4-trifluoroacetone) have been studied using cyclic voltammetry (CV). Their redox behaviors including oxidation and/ or reduction process for both central atom and tta ligand have been discussed. The cyclic voltammogrammes display one irreversible oxidation peak in a positive potential region, where it appears in the area between + 1.30 and + 1.95 V based on the type of complex. In addition, two reduction peaks are appeared in the negative region potentials, at the region between – 1.06 to – 2.16 V. The irreversible oxidation potential peak of thienyl ring has shifted to the lower positive potential, while the reversibly redox potential peak of the fluorinated--diketone moiety shifts to the higher negative potential compared with non-coordinated H-tta ligand. The spectral properties, energy levels, and energy gap for the respective complexes have been verified with UV-Vis spectrophotometer.
VL  - 2
IS  - 1
ER  -

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Author Information

Mohammed A. Al-Anber

Department of Chemical Science, Faculty of Science, Mu′tah University, 61710 Al-Karak, P.O. Box 7, Jordan

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Mohammed A. Al-Anber. (2013). Electrochemical Behaviour and Electronic Absorption of the Metal β- Diketonates Complexes. American Journal of Physical Chemistry, 2(1), 1-7. https://doi.org/10.11648/j.ajpc.20130201.11

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ACS Style

Mohammed A. Al-Anber. Electrochemical Behaviour and Electronic Absorption of the Metal β- Diketonates Complexes. Am. J. Phys. Chem. 2013, 2(1), 1-7. doi: 10.11648/j.ajpc.20130201.11

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AMA Style

Mohammed A. Al-Anber. Electrochemical Behaviour and Electronic Absorption of the Metal β- Diketonates Complexes. Am J Phys Chem. 2013;2(1):1-7. doi: 10.11648/j.ajpc.20130201.11

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@article{10.11648/j.ajpc.20130201.11,
  author = {Mohammed A. Al-Anber},
  title = {Electrochemical Behaviour and Electronic Absorption of the Metal β- Diketonates Complexes},
  journal = {American Journal of Physical Chemistry},
  volume = {2},
  number = {1},
  pages = {1-7},
  doi = {10.11648/j.ajpc.20130201.11},
  url = {https://doi.org/10.11648/j.ajpc.20130201.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpc.20130201.11},
  abstract = {The electrochemical properties of -diketonate complexes, such as [Co(tta)2(H2O)2], [Ni(tta)2(H2O)2], [Cu(tta)2] and [Zn(tta)2(H2O)2] (tta = deprotonated of  1-thenoyl-4,4,4-trifluoroacetone) have been studied using cyclic voltammetry (CV). Their redox behaviors including oxidation and/ or reduction process for both central atom and tta ligand have been discussed. The cyclic voltammogrammes display one irreversible oxidation peak in a positive potential region, where it appears in the area between + 1.30 and + 1.95 V based on the type of complex. In addition, two reduction peaks are appeared in the negative region potentials, at the region between – 1.06 to – 2.16 V. The irreversible oxidation potential peak of thienyl ring has shifted to the lower positive potential, while the reversibly redox potential peak of the fluorinated--diketone moiety shifts to the higher negative potential compared with non-coordinated H-tta ligand. The spectral properties, energy levels, and energy gap for the respective complexes have been verified with UV-Vis spectrophotometer.},
 year = {2013}
}

Copy | Download

TY  - JOUR
T1  - Electrochemical Behaviour and Electronic Absorption of the Metal β- Diketonates Complexes
AU  - Mohammed A. Al-Anber
Y1  - 2013/02/20
PY  - 2013
N1  - https://doi.org/10.11648/j.ajpc.20130201.11
DO  - 10.11648/j.ajpc.20130201.11
T2  - American Journal of Physical Chemistry
JF  - American Journal of Physical Chemistry
JO  - American Journal of Physical Chemistry
SP  - 1
EP  - 7
PB  - Science Publishing Group
SN  - 2327-2449
UR  - https://doi.org/10.11648/j.ajpc.20130201.11
AB  - The electrochemical properties of -diketonate complexes, such as [Co(tta)2(H2O)2], [Ni(tta)2(H2O)2], [Cu(tta)2] and [Zn(tta)2(H2O)2] (tta = deprotonated of  1-thenoyl-4,4,4-trifluoroacetone) have been studied using cyclic voltammetry (CV). Their redox behaviors including oxidation and/ or reduction process for both central atom and tta ligand have been discussed. The cyclic voltammogrammes display one irreversible oxidation peak in a positive potential region, where it appears in the area between + 1.30 and + 1.95 V based on the type of complex. In addition, two reduction peaks are appeared in the negative region potentials, at the region between – 1.06 to – 2.16 V. The irreversible oxidation potential peak of thienyl ring has shifted to the lower positive potential, while the reversibly redox potential peak of the fluorinated--diketone moiety shifts to the higher negative potential compared with non-coordinated H-tta ligand. The spectral properties, energy levels, and energy gap for the respective complexes have been verified with UV-Vis spectrophotometer.
VL  - 2
IS  - 1
ER  -

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