Thermochemistry of Heteroatomic Compounds: Analysis and Calculation of Thermody-namic Functions of Amino Acids and Some Peptides of Different Space Structure

Vitaly Vitalevich Ovchinnikov

doi:doi:10.11648/j.ajpc.20130201.12

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Thermochemistry of Heteroatomic Compounds: Analysis and Calculation of Thermody-namic Functions of Amino Acids and Some Peptides of Different Space Structure

Vitaly Vitalevich Ovchinnikov

Published in American Journal of Physical Chemistry (Volume 2, Issue 1)

Published: 20 February 2013

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Abstract

The values of free energies, the heats of combustion and formation in condensed and gaseous phases over 30 amino acids of different structure were analyzed. Entropies and heat capacities in standard conditions were considered too. Twenty one equations of such type as Yо = i ± f (N – g) +Σ(hc)j, in which Yо is thermodynamic function or heat capaci-ty, i and f are stoichiometric coefficiens, Σ(hc)j are the sums of the number (j) of the heat corrections for the mentioned thermodynamic magnitudes, N is the number of valence electrons, from which a number of lone electron pairs (g) is ex-cepted for. The obtained equations were used for the calculations of a new such parameters for four phosphorylated amino acids, two enkephalines and two human peptides of low molecular weights.

Published in	American Journal of Physical Chemistry (Volume 2, Issue 1)
DOI	10.11648/j.ajpc.20130201.12
Page(s)	8-15
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2013. Published by Science Publishing Group

Keywords

Amino Acid, Free Energy of Combustion, Free Energy of Formation, Heat of Combustion Heat of Formation, Entropy, Heat Capacity, Enkephalines, Peptides

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Vitaly Vitalevich Ovchinnikov. (2013). Thermochemistry of Heteroatomic Compounds: Analysis and Calculation of Thermody-namic Functions of Amino Acids and Some Peptides of Different Space Structure. American Journal of Physical Chemistry, 2(1), 8-15. https://doi.org/10.11648/j.ajpc.20130201.12

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ACS Style

Vitaly Vitalevich Ovchinnikov. Thermochemistry of Heteroatomic Compounds: Analysis and Calculation of Thermody-namic Functions of Amino Acids and Some Peptides of Different Space Structure. Am. J. Phys. Chem. 2013, 2(1), 8-15. doi: 10.11648/j.ajpc.20130201.12

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AMA Style

Vitaly Vitalevich Ovchinnikov. Thermochemistry of Heteroatomic Compounds: Analysis and Calculation of Thermody-namic Functions of Amino Acids and Some Peptides of Different Space Structure. Am J Phys Chem. 2013;2(1):8-15. doi: 10.11648/j.ajpc.20130201.12

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@article{10.11648/j.ajpc.20130201.12,
  author = {Vitaly Vitalevich Ovchinnikov},
  title = {Thermochemistry of Heteroatomic Compounds: Analysis and Calculation of Thermody-namic Functions of Amino Acids and Some Peptides of Different Space Structure},
  journal = {American Journal of Physical Chemistry},
  volume = {2},
  number = {1},
  pages = {8-15},
  doi = {10.11648/j.ajpc.20130201.12},
  url = {https://doi.org/10.11648/j.ajpc.20130201.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpc.20130201.12},
  abstract = {The values of free energies, the heats of combustion and formation in condensed and gaseous phases over 30 amino acids of different structure were analyzed. Entropies and heat capacities in standard conditions were considered too. Twenty one equations of such type as Yо = i ± f (N – g) +Σ(hc)j, in which Yо is thermodynamic function or heat capaci-ty, i and f are stoichiometric coefficiens, Σ(hc)j are the sums of the number (j) of the heat corrections for the mentioned thermodynamic magnitudes, N is the number of valence electrons, from which a number of lone electron pairs (g) is ex-cepted for. The obtained equations were used for the calculations of a new such parameters for four phosphorylated amino acids, two enkephalines and two human peptides of low molecular weights.},
 year = {2013}
}

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TY  - JOUR
T1  - Thermochemistry of Heteroatomic Compounds: Analysis and Calculation of Thermody-namic Functions of Amino Acids and Some Peptides of Different Space Structure
AU  - Vitaly Vitalevich Ovchinnikov
Y1  - 2013/02/20
PY  - 2013
N1  - https://doi.org/10.11648/j.ajpc.20130201.12
DO  - 10.11648/j.ajpc.20130201.12
T2  - American Journal of Physical Chemistry
JF  - American Journal of Physical Chemistry
JO  - American Journal of Physical Chemistry
SP  - 8
EP  - 15
PB  - Science Publishing Group
SN  - 2327-2449
UR  - https://doi.org/10.11648/j.ajpc.20130201.12
AB  - The values of free energies, the heats of combustion and formation in condensed and gaseous phases over 30 amino acids of different structure were analyzed. Entropies and heat capacities in standard conditions were considered too. Twenty one equations of such type as Yо = i ± f (N – g) +Σ(hc)j, in which Yо is thermodynamic function or heat capaci-ty, i and f are stoichiometric coefficiens, Σ(hc)j are the sums of the number (j) of the heat corrections for the mentioned thermodynamic magnitudes, N is the number of valence electrons, from which a number of lone electron pairs (g) is ex-cepted for. The obtained equations were used for the calculations of a new such parameters for four phosphorylated amino acids, two enkephalines and two human peptides of low molecular weights.
VL  - 2
IS  - 1
ER  -

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Author Information

Vitaly Vitalevich Ovchinnikov

Department of General Chemistry and Ecology, Tupolev Kazan National Researching Technical University, St-K.Marks 10, 420111 Kazan, Tatarstan, Russia

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APA Style

Vitaly Vitalevich Ovchinnikov. (2013). Thermochemistry of Heteroatomic Compounds: Analysis and Calculation of Thermody-namic Functions of Amino Acids and Some Peptides of Different Space Structure. American Journal of Physical Chemistry, 2(1), 8-15. https://doi.org/10.11648/j.ajpc.20130201.12

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ACS Style

Vitaly Vitalevich Ovchinnikov. Thermochemistry of Heteroatomic Compounds: Analysis and Calculation of Thermody-namic Functions of Amino Acids and Some Peptides of Different Space Structure. Am. J. Phys. Chem. 2013, 2(1), 8-15. doi: 10.11648/j.ajpc.20130201.12

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AMA Style

Vitaly Vitalevich Ovchinnikov. Thermochemistry of Heteroatomic Compounds: Analysis and Calculation of Thermody-namic Functions of Amino Acids and Some Peptides of Different Space Structure. Am J Phys Chem. 2013;2(1):8-15. doi: 10.11648/j.ajpc.20130201.12

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@article{10.11648/j.ajpc.20130201.12,
  author = {Vitaly Vitalevich Ovchinnikov},
  title = {Thermochemistry of Heteroatomic Compounds: Analysis and Calculation of Thermody-namic Functions of Amino Acids and Some Peptides of Different Space Structure},
  journal = {American Journal of Physical Chemistry},
  volume = {2},
  number = {1},
  pages = {8-15},
  doi = {10.11648/j.ajpc.20130201.12},
  url = {https://doi.org/10.11648/j.ajpc.20130201.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpc.20130201.12},
  abstract = {The values of free energies, the heats of combustion and formation in condensed and gaseous phases over 30 amino acids of different structure were analyzed. Entropies and heat capacities in standard conditions were considered too. Twenty one equations of such type as Yо = i ± f (N – g) +Σ(hc)j, in which Yо is thermodynamic function or heat capaci-ty, i and f are stoichiometric coefficiens, Σ(hc)j are the sums of the number (j) of the heat corrections for the mentioned thermodynamic magnitudes, N is the number of valence electrons, from which a number of lone electron pairs (g) is ex-cepted for. The obtained equations were used for the calculations of a new such parameters for four phosphorylated amino acids, two enkephalines and two human peptides of low molecular weights.},
 year = {2013}
}

Copy | Download

TY  - JOUR
T1  - Thermochemistry of Heteroatomic Compounds: Analysis and Calculation of Thermody-namic Functions of Amino Acids and Some Peptides of Different Space Structure
AU  - Vitaly Vitalevich Ovchinnikov
Y1  - 2013/02/20
PY  - 2013
N1  - https://doi.org/10.11648/j.ajpc.20130201.12
DO  - 10.11648/j.ajpc.20130201.12
T2  - American Journal of Physical Chemistry
JF  - American Journal of Physical Chemistry
JO  - American Journal of Physical Chemistry
SP  - 8
EP  - 15
PB  - Science Publishing Group
SN  - 2327-2449
UR  - https://doi.org/10.11648/j.ajpc.20130201.12
AB  - The values of free energies, the heats of combustion and formation in condensed and gaseous phases over 30 amino acids of different structure were analyzed. Entropies and heat capacities in standard conditions were considered too. Twenty one equations of such type as Yо = i ± f (N – g) +Σ(hc)j, in which Yо is thermodynamic function or heat capaci-ty, i and f are stoichiometric coefficiens, Σ(hc)j are the sums of the number (j) of the heat corrections for the mentioned thermodynamic magnitudes, N is the number of valence electrons, from which a number of lone electron pairs (g) is ex-cepted for. The obtained equations were used for the calculations of a new such parameters for four phosphorylated amino acids, two enkephalines and two human peptides of low molecular weights.
VL  - 2
IS  - 1
ER  -

Copy | Download