Structural, Thermal and Electrical Studies of Al2O3 Nanoparticle Soaked Electrolyte Gel Films for Novel Proton Conducting (H+ ion) Eco-friendly Device Applications

Neelesh Rai; Chandra Prakash Singh; Lovely Ranjta

doi:doi:10.11648/j.nano.20221001.11

| Peer-Reviewed

Structural, Thermal and Electrical Studies of Al₂O₃ Nanoparticle Soaked Electrolyte Gel Films for Novel Proton Conducting (H⁺ ion) Eco-friendly Device Applications

Neelesh Rai, Chandra Prakash Singh, Lovely Ranjta

Published in American Journal of Nano Research and Applications (Volume 10, Issue 1)

Received: 20 April 2022 Accepted: 10 May 2022 Published: 31 May 2022

Views: Downloads:

Download PDF

Share This Article

Twitter
Linked In
Facebook

Abstract

An attempt has been made to prepare and characterize ammonium acetate (NH₄CH₃COO) salt and Aluminium Oxide (Al₂O₃)-soaked polyvinyl alcohol (PVA) based [PVA-NH₄CH₃COO:×wt%Al₂O₃] system nanocomposite polymer gel electrolyte (NCPGE) films using a solution cast technique. The SEM and XRD studies revealed improvement in amorphous nature. The degree of crystallinity and average crystallite size of electrolytes with respect to Al₂O₃ were projected to ascertain improvement in amorphous nature. FTIR studies confirmed the complexation between PVA, NH₄CH₃COO and Al₂O₃. The DSC studies show better thermal response upon addition of Al₂O₃ nanofiller. TGA studies reveal the mass of nanocomposite polymer gel electrolyte decreases continuously with increase in the Al₂O₃ nanofiller contents. Closer assessment of conductivity behavior shows two maximas: one around 0.5wt% and the other around 1wt% filler concentration which is a typical feature for nanocomposite gel polymer electrolytes. The temperature dependence of electrical conductivity shows a combination of Arrhenius and Vogel–Tamman–Fulcher (VTF) behavior. The ionic conductivity is found to increase with addition of filler concentration and optimum ionic conductivity of 3.88×10⁻⁴ Scm⁻¹ with wide electrochemical stability of ±4.78V is achieved at 1wt% Al₂O₃ nano filler and confirms the availability of H⁺ ion (proton) in the system suitable for the development of environment friendly rechargeable batteries application.

Published in	American Journal of Nano Research and Applications (Volume 10, Issue 1)
DOI	10.11648/j.nano.20221001.11
Page(s)	1-8
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2022. Published by Science Publishing Group

Keywords

XRD, DSC, Conductivity, Nanocomposite Polymer Gel Electrolytes, Proton-Conducting Batteries

References

[1]	Verma, M. L., Minakshi, M., & Singh, N. K. (2014). Synthesis & characterization of solid polymer electrolyte based on activated carbon for solid state capacitor. Electrochimica Acta, 137, 497-503. doi: 10.1016/j.electacta.2014.06.039.
[2]	Zhou, D., Shanmukaraj, D., Tkacheva, A., Armand, M., & Wang, G. (2019). Polymer Electrolytes for Lithium-Based Batteries: Advances and Prospects. Chem, 5 (9), 2326-2352. doi: https://doi.org/10.1016/j.chempr.2019.05.009.
[3]	Cheng, X., Pan, J., Zhao, Y., & Liao, M. (2017). Gel Polymer Electrolytes for Electrochemical Energy Storage. Advanced Energy Materials, 8 (7): 1702184. doi: 10.1002/aenm.201702184.
[4]	Wen, P., Zhao, Y., Wang, Z., Lin, J., Chen, M., & Lin, X. (2021). Solvent-Free Synthesis of the Polymer Electrolyte via Photo-Controlled Radical Polymerization: Toward Ultrafast In-Built Fabrication of Solid-State Batteries under Visible Light. ACS Applied Materials And Interfaces, 13 (7), 8426–8434. doi: https://doi.org/10.1021/acsami.0c21461.
[5]	Jeon, J. K., Kwak, S. Y., & Cho, B. W. (2005). Solvent-Free Polymer Electrolytes. Journal Of The Electrochemical Society, 152 (8), 1583-1589. doi: 10.1149/1.1939167.
[6]	Kumar, K. N., Vijayalakshmi, L., & Ratnakaram, Y. C. (2015). Energy transfer based photoluminescence properties of (Sm³⁺ + Eu³⁺): PEO+PVP polymer films for red luminescent display device applications. Optical Materials, 45, 148-155. doi: 10.1016/J.OPMAT.2015.03.025.
[7]	Eltoun, M. S. A., Nasr, R. M. O., & Omer, H. M. A. (2020). Preparation and characterization of CuO nanoparticles using sol-gel method and its application as CuO/Al₂O₃. American Journal of Nano Research and applications, 8 (2), 16-21. doi: 10.11648/j.nano.20200802.
[8]	Wu, H. D., Wu, I. D., & Chang, F. C. (2001). The interaction behavior of polymer electrolytes composed of poly (vinyl pyrrolidone) and lithium perchlorate (LiClO₄). Polymer, 42 (2), 555-562. doi.org/10.1016/S0032-3861(00)00213-5.
[9]	Song, M. K., Kim, Y. T., & Tae, Y. (2003). Thermally Stable Gel Polymer Electrolytes. Journal of The Electrochemical Society, 150 (4), 439-444. doi: 10.1149/1.1556592.
[10]	Huy, V. P. H., So, S., & Hur J. (2021). Inorganic Fillers in Composite Gel Polymer Electrolytes for High-Performance Lithium and Non-Lithium Polymer Batteries. Nanomaterials, 11 (3), 614. doi: 10.3390/nano11030614.
[11]	Stephan, A. M., & Nahm, K. S. (2006). Review on composite polymer electrolytes for lithium batteries. Polymer, 47 (16), 5952-5964. doi: 10.1016/j.polymer.2006.05.069.
[12]	Chand, N., Rai, N., Agrawal, S. L., & Patel, S. K. (2011). Morphology, thermal, electrical and electrochemical stability of nano aluminium-oxide-filled polyvinyl alcohol composite gel electrolyte. Bulletin Of Material Science, 34 (7), 1297-1304. doi: 10.1007/s12034-011-0318-7.
[13]	Awadhia, A., & Agrawal, S. L. (2007). Structural, thermal and electrical characterizations of PVA:DMSO:NH₄SCN gel electrolytes. Solid State Ionics, 178 (13-14), 951-958. doi: 10.1016/j.ssi.2007.04.001.
[14]	Agrawal, S. L., Rai, N., Natarajan, T. S., & Chand, N. (2013). Electrical characterization of PVA-based nanocomposite electrolyte nanofibre mats doped with a multiwalled carbon nanotube. Ionics, 19, 145-154. doi: 10.1007/s11581-012-0713-0.
[15]	Deepa, M., Sharma, N., Agnihotry, S. A., & Chandra, R. (2002). FTIR investigations on ion-ion interactions in liquid and gel polymeric electrolytes: LiCF₃SO₃-PC-PMMA. Journal Of Materials Science, 37, 1759-1765. doi: 10.1023/A:1014921101649.
[16]	Ghezelbash, Z., Ashouri, D., Mousavian, S., Ghandi, A. H., & Rahnama, Y. (2012). Surface modified Al₂O₃ in fluorinated polyimide/Al₂O₃ nanoparticles: Synthesis and characterization. Bulletin Of Materials Science, 35, 925-931. doi: 10.1007/s12034-012-0385-4.
[17]	Chand, N., Rai, N., Natarajan, T. S., & Agrawal, S. L. (2011). Fabrication and Characterization of nano Al₂O₃ filled PVA: NH₄SCN Electrolyte Nanofibers by Electrospinning. Fibers and Polymers, 12 (4), 438-443. doi: https://doi.org/10.1007/s12221-011-0438-0.
[18]	Agrawal, S. L., & Shukla, P. K. (2000). Structural and electrical characterization of polymeric electrolytes: PVA-NH₄SCN system. Indian Journal Of Pure And Applied Physics, 38, 53-61.
[19]	Agrawal, S. L., & Awadhia, A. (2004). DSC and conductivity studies on PVA based proton conducting gel electrolytes. Bulletin of Materials Science, 27, 523-527. doi: 10.1007/BF02707280.
[20]	Mukherjee, G. S., Shukla, N., Singh, R. K., & Mathur, G. N. (2004). Studies on the properties of carboxymethylated polyvinyl alcohol. Journal Of Scientific And Industrial Research, 63, 596-602.
[21]	Dibbern, D. B., & Atvars, T. D. Z. (2000). Thermal transitions of poly(vinyl alcohol) hydrogel sensed by a fluorescent probe. Journal Of Applied Polymer Science, 75 (6), 815-824. doi: 10.1002/(SICI)1097-4628(20000207)75:6<815:AID-APP11>3.0.CO;2-0.
[22]	Zou, G. X., Jin, P. Q., & Xin, L. Z. (2008). Extruded Starch/PVA Composites: Water Resistance, Thermal Properties, and Morphology. Journal Of Elastomers and Plastics, 40, 303-316. doi: 10.1177/0095244307085787.
[23]	Sharma, S., Dhiman, N., Pathak, D., & Kumar, R. (2016). Effect of Donor Number of Plasticizers on Conductivity of Polymer Electrolytes Containing NH₄F. i-Manager’s Journal On Material Science, 3 (4), 28-34. doi: 10.26634/jms.3.4.4825.
[24]	Ito, T., Sun, L., & Crooks, R. M. (2003). Electrochemical Etching of Individual Multiwall Carbon Nanotubes. Electrochemical And Solid-State Letters 6 (1), C4-C7.
[25]	Hinds, B. J., Chopra, N., Rantell, T., Andrews, R., Gavalas, V., & Bachas, L. G. (2004). Aligned Multiwalled Carbon Nanotube Membranes. Science, 303, 62-65. doi: 10.1126/science.1092048.
[26]	Haque, M. A., Sulong, A. B., Shyuan, L. K., Majlan, E. H., Husaini, T., & Rosli, R. E. (2021). Synthesis of polymer/MWCNT nanocomposite catalyst supporting materials for high-temperature PEM fuel cells. International Journal of Hydrogen Energy, 46 (5) 4339-4353. doi: 10.1016/j.ijhydene.2020.10.223.
[27]	Ranjta, L., Singh, C. P., & Rai, N. (2022). Experimental investigations on nano-ferrite embedded nanocomposite polymer electrolytes for proton-conducting rechargeable batteries application. Materials Today: Proceedings, 54 (3), 702–709. doi: 10.1016/j.matpr.2021.10.408.

Cite This Article

Plain Text BibTeX RIS

APA Style

Neelesh Rai, Chandra Prakash Singh, Lovely Ranjta. (2022). Structural, Thermal and Electrical Studies of Al2O3 Nanoparticle Soaked Electrolyte Gel Films for Novel Proton Conducting (H+ ion) Eco-friendly Device Applications. American Journal of Nano Research and Applications, 10(1), 1-8. https://doi.org/10.11648/j.nano.20221001.11

Copy | Download

ACS Style

Neelesh Rai; Chandra Prakash Singh; Lovely Ranjta. Structural, Thermal and Electrical Studies of Al2O3 Nanoparticle Soaked Electrolyte Gel Films for Novel Proton Conducting (H+ ion) Eco-friendly Device Applications. Am. J. Nano Res. Appl. 2022, 10(1), 1-8. doi: 10.11648/j.nano.20221001.11

Copy | Download

AMA Style

Neelesh Rai, Chandra Prakash Singh, Lovely Ranjta. Structural, Thermal and Electrical Studies of Al2O3 Nanoparticle Soaked Electrolyte Gel Films for Novel Proton Conducting (H+ ion) Eco-friendly Device Applications. Am J Nano Res Appl. 2022;10(1):1-8. doi: 10.11648/j.nano.20221001.11

Copy | Download

@article{10.11648/j.nano.20221001.11,
  author = {Neelesh Rai and Chandra Prakash Singh and Lovely Ranjta},
  title = {Structural, Thermal and Electrical Studies of Al2O3 Nanoparticle Soaked Electrolyte Gel Films for Novel Proton Conducting (H+ ion) Eco-friendly Device Applications},
  journal = {American Journal of Nano Research and Applications},
  volume = {10},
  number = {1},
  pages = {1-8},
  doi = {10.11648/j.nano.20221001.11},
  url = {https://doi.org/10.11648/j.nano.20221001.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.nano.20221001.11},
  abstract = {An attempt has been made to prepare and characterize ammonium acetate (NH4CH3COO) salt and Aluminium Oxide (Al2O3)-soaked polyvinyl alcohol (PVA) based [PVA-NH4CH3COO:×wt%Al2O3] system nanocomposite polymer gel electrolyte (NCPGE) films using a solution cast technique. The SEM and XRD studies revealed improvement in amorphous nature. The degree of crystallinity and average crystallite size of electrolytes with respect to Al2O3 were projected to ascertain improvement in amorphous nature. FTIR studies confirmed the complexation between PVA, NH4CH3COO and Al2O3. The DSC studies show better thermal response upon addition of Al2O3 nanofiller. TGA studies reveal the mass of nanocomposite polymer gel electrolyte decreases continuously with increase in the Al2O3 nanofiller contents. Closer assessment of conductivity behavior shows two maximas: one around 0.5wt% and the other around 1wt% filler concentration which is a typical feature for nanocomposite gel polymer electrolytes. The temperature dependence of electrical conductivity shows a combination of Arrhenius and Vogel–Tamman–Fulcher (VTF) behavior. The ionic conductivity is found to increase with addition of filler concentration and optimum ionic conductivity of 3.88×10−4 Scm−1 with wide electrochemical stability of ±4.78V is achieved at 1wt% Al2O3 nano filler and confirms the availability of H+ ion (proton) in the system suitable for the development of environment friendly rechargeable batteries application.},
 year = {2022}
}

Copy | Download

TY  - JOUR
T1  - Structural, Thermal and Electrical Studies of Al2O3 Nanoparticle Soaked Electrolyte Gel Films for Novel Proton Conducting (H+ ion) Eco-friendly Device Applications
AU  - Neelesh Rai
AU  - Chandra Prakash Singh
AU  - Lovely Ranjta
Y1  - 2022/05/31
PY  - 2022
N1  - https://doi.org/10.11648/j.nano.20221001.11
DO  - 10.11648/j.nano.20221001.11
T2  - American Journal of Nano Research and Applications
JF  - American Journal of Nano Research and Applications
JO  - American Journal of Nano Research and Applications
SP  - 1
EP  - 8
PB  - Science Publishing Group
SN  - 2575-3738
UR  - https://doi.org/10.11648/j.nano.20221001.11
AB  - An attempt has been made to prepare and characterize ammonium acetate (NH4CH3COO) salt and Aluminium Oxide (Al2O3)-soaked polyvinyl alcohol (PVA) based [PVA-NH4CH3COO:×wt%Al2O3] system nanocomposite polymer gel electrolyte (NCPGE) films using a solution cast technique. The SEM and XRD studies revealed improvement in amorphous nature. The degree of crystallinity and average crystallite size of electrolytes with respect to Al2O3 were projected to ascertain improvement in amorphous nature. FTIR studies confirmed the complexation between PVA, NH4CH3COO and Al2O3. The DSC studies show better thermal response upon addition of Al2O3 nanofiller. TGA studies reveal the mass of nanocomposite polymer gel electrolyte decreases continuously with increase in the Al2O3 nanofiller contents. Closer assessment of conductivity behavior shows two maximas: one around 0.5wt% and the other around 1wt% filler concentration which is a typical feature for nanocomposite gel polymer electrolytes. The temperature dependence of electrical conductivity shows a combination of Arrhenius and Vogel–Tamman–Fulcher (VTF) behavior. The ionic conductivity is found to increase with addition of filler concentration and optimum ionic conductivity of 3.88×10−4 Scm−1 with wide electrochemical stability of ±4.78V is achieved at 1wt% Al2O3 nano filler and confirms the availability of H+ ion (proton) in the system suitable for the development of environment friendly rechargeable batteries application.
VL  - 10
IS  - 1
ER  -

Copy | Download

Author Information

Neelesh Rai

Department of Physics, AKS University, Satna, India
Chandra Prakash Singh

Department of Physics, AKS University, Satna, India
Lovely Ranjta

Department of Physics, AKS University, Satna, India

Download PDF

Sections

Plain Text BibTeX RIS

APA Style

Neelesh Rai, Chandra Prakash Singh, Lovely Ranjta. (2022). Structural, Thermal and Electrical Studies of Al2O3 Nanoparticle Soaked Electrolyte Gel Films for Novel Proton Conducting (H+ ion) Eco-friendly Device Applications. American Journal of Nano Research and Applications, 10(1), 1-8. https://doi.org/10.11648/j.nano.20221001.11

Copy | Download

ACS Style

Neelesh Rai; Chandra Prakash Singh; Lovely Ranjta. Structural, Thermal and Electrical Studies of Al2O3 Nanoparticle Soaked Electrolyte Gel Films for Novel Proton Conducting (H+ ion) Eco-friendly Device Applications. Am. J. Nano Res. Appl. 2022, 10(1), 1-8. doi: 10.11648/j.nano.20221001.11

Copy | Download

AMA Style

Neelesh Rai, Chandra Prakash Singh, Lovely Ranjta. Structural, Thermal and Electrical Studies of Al2O3 Nanoparticle Soaked Electrolyte Gel Films for Novel Proton Conducting (H+ ion) Eco-friendly Device Applications. Am J Nano Res Appl. 2022;10(1):1-8. doi: 10.11648/j.nano.20221001.11

Copy | Download

@article{10.11648/j.nano.20221001.11,
  author = {Neelesh Rai and Chandra Prakash Singh and Lovely Ranjta},
  title = {Structural, Thermal and Electrical Studies of Al2O3 Nanoparticle Soaked Electrolyte Gel Films for Novel Proton Conducting (H+ ion) Eco-friendly Device Applications},
  journal = {American Journal of Nano Research and Applications},
  volume = {10},
  number = {1},
  pages = {1-8},
  doi = {10.11648/j.nano.20221001.11},
  url = {https://doi.org/10.11648/j.nano.20221001.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.nano.20221001.11},
  abstract = {An attempt has been made to prepare and characterize ammonium acetate (NH4CH3COO) salt and Aluminium Oxide (Al2O3)-soaked polyvinyl alcohol (PVA) based [PVA-NH4CH3COO:×wt%Al2O3] system nanocomposite polymer gel electrolyte (NCPGE) films using a solution cast technique. The SEM and XRD studies revealed improvement in amorphous nature. The degree of crystallinity and average crystallite size of electrolytes with respect to Al2O3 were projected to ascertain improvement in amorphous nature. FTIR studies confirmed the complexation between PVA, NH4CH3COO and Al2O3. The DSC studies show better thermal response upon addition of Al2O3 nanofiller. TGA studies reveal the mass of nanocomposite polymer gel electrolyte decreases continuously with increase in the Al2O3 nanofiller contents. Closer assessment of conductivity behavior shows two maximas: one around 0.5wt% and the other around 1wt% filler concentration which is a typical feature for nanocomposite gel polymer electrolytes. The temperature dependence of electrical conductivity shows a combination of Arrhenius and Vogel–Tamman–Fulcher (VTF) behavior. The ionic conductivity is found to increase with addition of filler concentration and optimum ionic conductivity of 3.88×10−4 Scm−1 with wide electrochemical stability of ±4.78V is achieved at 1wt% Al2O3 nano filler and confirms the availability of H+ ion (proton) in the system suitable for the development of environment friendly rechargeable batteries application.},
 year = {2022}
}

Copy | Download

TY  - JOUR
T1  - Structural, Thermal and Electrical Studies of Al2O3 Nanoparticle Soaked Electrolyte Gel Films for Novel Proton Conducting (H+ ion) Eco-friendly Device Applications
AU  - Neelesh Rai
AU  - Chandra Prakash Singh
AU  - Lovely Ranjta
Y1  - 2022/05/31
PY  - 2022
N1  - https://doi.org/10.11648/j.nano.20221001.11
DO  - 10.11648/j.nano.20221001.11
T2  - American Journal of Nano Research and Applications
JF  - American Journal of Nano Research and Applications
JO  - American Journal of Nano Research and Applications
SP  - 1
EP  - 8
PB  - Science Publishing Group
SN  - 2575-3738
UR  - https://doi.org/10.11648/j.nano.20221001.11
AB  - An attempt has been made to prepare and characterize ammonium acetate (NH4CH3COO) salt and Aluminium Oxide (Al2O3)-soaked polyvinyl alcohol (PVA) based [PVA-NH4CH3COO:×wt%Al2O3] system nanocomposite polymer gel electrolyte (NCPGE) films using a solution cast technique. The SEM and XRD studies revealed improvement in amorphous nature. The degree of crystallinity and average crystallite size of electrolytes with respect to Al2O3 were projected to ascertain improvement in amorphous nature. FTIR studies confirmed the complexation between PVA, NH4CH3COO and Al2O3. The DSC studies show better thermal response upon addition of Al2O3 nanofiller. TGA studies reveal the mass of nanocomposite polymer gel electrolyte decreases continuously with increase in the Al2O3 nanofiller contents. Closer assessment of conductivity behavior shows two maximas: one around 0.5wt% and the other around 1wt% filler concentration which is a typical feature for nanocomposite gel polymer electrolytes. The temperature dependence of electrical conductivity shows a combination of Arrhenius and Vogel–Tamman–Fulcher (VTF) behavior. The ionic conductivity is found to increase with addition of filler concentration and optimum ionic conductivity of 3.88×10−4 Scm−1 with wide electrochemical stability of ±4.78V is achieved at 1wt% Al2O3 nano filler and confirms the availability of H+ ion (proton) in the system suitable for the development of environment friendly rechargeable batteries application.
VL  - 10
IS  - 1
ER  -

Copy | Download