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Ionic Liquids-β-Cyclodextrin Polymer for Separation/Analysis Allura Red in Food Samples

Received: 26 January 2017     Accepted: 13 February 2017     Published: 2 March 2017
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Abstract

Ionic liquids β-cyclodextrin polymer (mono-6-deoxy-6-(1-ethyl-imidazolium)-β-cyclodextrin iodide polymer, ILs-β-CDCP) was synthesized. A novel method based on ILs-β-CDCP solid phase extraction coupled with UV-visible spectrophotometry for the preconcentration / separation allura red (AR) was investigated. The results was shown that AR was adsorbed on ILs-β-CDCP and eluted with sodium dodecyl sulfate (SDS) (1%) rapidly. Under the optimum conditions, the preconcentration factor for AR was 27. The linear range, detection limit (DL), correlation coefficient (R) and relative standard deviation (RSD) were found to be 0.10-9.00 μg/mL, 5.2 μg/L, 0.9987 and 3.10% (n=3, c=4.00 μg/mL), respectively. The adsorption mechanism of ILs-β-CDCP on AR was studied through the FTIR analysis and the inclusion constant of ILs-β-CDCP-AR. This proposed method has been successfully applied to the determination of AR in food samples.

Published in International Journal of Bioorganic Chemistry (Volume 2, Issue 1)
DOI 10.11648/j.ijbc.20170201.15
Page(s) 30-35
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2017. Published by Science Publishing Group

Keywords

Allura Red, Ionic Liquids-β-Cyclodextrin Polymer, Solid-Phase Extraction, UV-visible Spectrophotometry

References
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  • APA Style

    Almojtaba AbdAlkhalig Ahmed Bakheet, Xiashi Zhu. (2017). Ionic Liquids-β-Cyclodextrin Polymer for Separation/Analysis Allura Red in Food Samples. International Journal of Bioorganic Chemistry, 2(1), 30-35. https://doi.org/10.11648/j.ijbc.20170201.15

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    ACS Style

    Almojtaba AbdAlkhalig Ahmed Bakheet; Xiashi Zhu. Ionic Liquids-β-Cyclodextrin Polymer for Separation/Analysis Allura Red in Food Samples. Int. J. Bioorg. Chem. 2017, 2(1), 30-35. doi: 10.11648/j.ijbc.20170201.15

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    AMA Style

    Almojtaba AbdAlkhalig Ahmed Bakheet, Xiashi Zhu. Ionic Liquids-β-Cyclodextrin Polymer for Separation/Analysis Allura Red in Food Samples. Int J Bioorg Chem. 2017;2(1):30-35. doi: 10.11648/j.ijbc.20170201.15

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  • @article{10.11648/j.ijbc.20170201.15,
      author = {Almojtaba AbdAlkhalig Ahmed Bakheet and Xiashi Zhu},
      title = {Ionic Liquids-β-Cyclodextrin Polymer for Separation/Analysis Allura Red in Food Samples},
      journal = {International Journal of Bioorganic Chemistry},
      volume = {2},
      number = {1},
      pages = {30-35},
      doi = {10.11648/j.ijbc.20170201.15},
      url = {https://doi.org/10.11648/j.ijbc.20170201.15},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijbc.20170201.15},
      abstract = {Ionic liquids β-cyclodextrin polymer (mono-6-deoxy-6-(1-ethyl-imidazolium)-β-cyclodextrin iodide polymer, ILs-β-CDCP) was synthesized. A novel method based on ILs-β-CDCP solid phase extraction coupled with UV-visible spectrophotometry for the preconcentration / separation allura red (AR) was investigated. The results was shown that AR was adsorbed on ILs-β-CDCP and eluted with sodium dodecyl sulfate (SDS) (1%) rapidly. Under the optimum conditions, the preconcentration factor for AR was 27. The linear range, detection limit (DL), correlation coefficient (R) and relative standard deviation (RSD) were found to be 0.10-9.00 μg/mL, 5.2 μg/L, 0.9987 and 3.10% (n=3, c=4.00 μg/mL), respectively. The adsorption mechanism of ILs-β-CDCP on AR was studied through the FTIR analysis and the inclusion constant of ILs-β-CDCP-AR. This proposed method has been successfully applied to the determination of AR in food samples.},
     year = {2017}
    }
    

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  • TY  - JOUR
    T1  - Ionic Liquids-β-Cyclodextrin Polymer for Separation/Analysis Allura Red in Food Samples
    AU  - Almojtaba AbdAlkhalig Ahmed Bakheet
    AU  - Xiashi Zhu
    Y1  - 2017/03/02
    PY  - 2017
    N1  - https://doi.org/10.11648/j.ijbc.20170201.15
    DO  - 10.11648/j.ijbc.20170201.15
    T2  - International Journal of Bioorganic Chemistry
    JF  - International Journal of Bioorganic Chemistry
    JO  - International Journal of Bioorganic Chemistry
    SP  - 30
    EP  - 35
    PB  - Science Publishing Group
    SN  - 2578-9392
    UR  - https://doi.org/10.11648/j.ijbc.20170201.15
    AB  - Ionic liquids β-cyclodextrin polymer (mono-6-deoxy-6-(1-ethyl-imidazolium)-β-cyclodextrin iodide polymer, ILs-β-CDCP) was synthesized. A novel method based on ILs-β-CDCP solid phase extraction coupled with UV-visible spectrophotometry for the preconcentration / separation allura red (AR) was investigated. The results was shown that AR was adsorbed on ILs-β-CDCP and eluted with sodium dodecyl sulfate (SDS) (1%) rapidly. Under the optimum conditions, the preconcentration factor for AR was 27. The linear range, detection limit (DL), correlation coefficient (R) and relative standard deviation (RSD) were found to be 0.10-9.00 μg/mL, 5.2 μg/L, 0.9987 and 3.10% (n=3, c=4.00 μg/mL), respectively. The adsorption mechanism of ILs-β-CDCP on AR was studied through the FTIR analysis and the inclusion constant of ILs-β-CDCP-AR. This proposed method has been successfully applied to the determination of AR in food samples.
    VL  - 2
    IS  - 1
    ER  - 

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Author Information
  • College of Chemistry & Chemical Engineering, Yangzhou University, Yangzhou, PR China

  • College of Chemistry & Chemical Engineering, Yangzhou University, Yangzhou, PR China

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