Copper (11) Ions Biosorption from Aqueous Solution Using Modified Moringa Oleiferal Leaves (MMOL)

Adebayo Oluwafemi Lawrence; Kenni Amoke Monisola; Oyetunde Julius Gbenga; Jegede Rufus Oluwafemi; Ajayi Margret Grace

doi:doi:10.11648/j.ajpc.20180702.11

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Copper (11) Ions Biosorption from Aqueous Solution Using Modified Moringa Oleiferal Leaves (MMOL)

Adebayo Oluwafemi Lawrence, Kenni Amoke Monisola, Oyetunde Julius Gbenga, Jegede Rufus Oluwafemi, Ajayi Margret Grace

Published in American Journal of Physical Chemistry (Volume 7, Issue 2)

Received: 11 February 2018 Accepted: 14 March 2018 Published: 1 June 2018

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Abstract

The present research work demonstrated the ability of MMOL in removing Copper (II) ions from an aqueous solution. The modified (MMOL) and unmodified moringaoleifera (UMOL) was characterized based on PZC and surface area. Isotherm experiments were conducted and the data obtained were fitted to Langmuir and Freundlich isotherm equations. The Freundlich equation gave the best description of the sorption process and the maximum saturated monolayer sorption capacity of the MMOL for CU (II) ions was 78.45 mg g^-1. The kinetics of the sorption process was studied by varying the initial CU (II) ions concentrations and the result obtained was analyzed by using pseudo-first-order and pseudo-second-order kinetic models. The pseudo second-order kinetic model was found to fit the experimental data for the entire sorption period with high coefficient of determination (r²). The effects of MMOL dose were studied using batch sorption system. The linear form of the Langmuir equation was used to analyze the data obtained when the sorbent dosage was optimized by method of continuous variation. The results obtained showed that the equilibrium monolayer sorption capacity, q_m, of the MMOL for CU (II) ions decreased (78.45 - 38.66 mg g^-1) with an increase in sorbent dosage. The result obtained from pH optimization showed that CU(II) ions removal increases with increase in CU(II) ions solution pH.

Published in	American Journal of Physical Chemistry (Volume 7, Issue 2)
DOI	10.11648/j.ajpc.20180702.11
Page(s)	12-18
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2018. Published by Science Publishing Group

Keywords

Biosorption, Kinetics, Modified Moringaoleifera Leaves, Pseudo First Order, Pseudo Second Order

References

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APA Style

Adebayo Oluwafemi Lawrence, Kenni Amoke Monisola, Oyetunde Julius Gbenga, Jegede Rufus Oluwafemi, Ajayi Margret Grace. (2018). Copper (11) Ions Biosorption from Aqueous Solution Using Modified Moringa Oleiferal Leaves (MMOL). American Journal of Physical Chemistry, 7(2), 12-18. https://doi.org/10.11648/j.ajpc.20180702.11

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ACS Style

Adebayo Oluwafemi Lawrence; Kenni Amoke Monisola; Oyetunde Julius Gbenga; Jegede Rufus Oluwafemi; Ajayi Margret Grace. Copper (11) Ions Biosorption from Aqueous Solution Using Modified Moringa Oleiferal Leaves (MMOL). Am. J. Phys. Chem. 2018, 7(2), 12-18. doi: 10.11648/j.ajpc.20180702.11

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AMA Style

Adebayo Oluwafemi Lawrence, Kenni Amoke Monisola, Oyetunde Julius Gbenga, Jegede Rufus Oluwafemi, Ajayi Margret Grace. Copper (11) Ions Biosorption from Aqueous Solution Using Modified Moringa Oleiferal Leaves (MMOL). Am J Phys Chem. 2018;7(2):12-18. doi: 10.11648/j.ajpc.20180702.11

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@article{10.11648/j.ajpc.20180702.11,
  author = {Adebayo Oluwafemi Lawrence and Kenni Amoke Monisola and Oyetunde Julius Gbenga and Jegede Rufus Oluwafemi and Ajayi Margret Grace},
  title = {Copper (11) Ions Biosorption from Aqueous Solution Using Modified Moringa Oleiferal Leaves (MMOL)},
  journal = {American Journal of Physical Chemistry},
  volume = {7},
  number = {2},
  pages = {12-18},
  doi = {10.11648/j.ajpc.20180702.11},
  url = {https://doi.org/10.11648/j.ajpc.20180702.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpc.20180702.11},
  abstract = {The present research work demonstrated the ability of MMOL in removing Copper (II) ions from an aqueous solution. The modified (MMOL) and unmodified moringaoleifera (UMOL) was characterized based on PZC and surface area. Isotherm experiments were conducted and the data obtained were fitted to Langmuir and Freundlich isotherm equations. The Freundlich equation gave the best description of the sorption process and the maximum saturated monolayer sorption capacity of the MMOL for CU (II) ions was 78.45 mg g-1. The kinetics of the sorption process was studied by varying the initial CU (II) ions concentrations and the result obtained was analyzed by using pseudo-first-order and pseudo-second-order kinetic models. The pseudo second-order kinetic model was found to fit the experimental data for the entire sorption period with high coefficient of determination (r2). The effects of MMOL dose were studied using batch sorption system. The linear form of the Langmuir equation was used to analyze the data obtained when the sorbent dosage was optimized by method of continuous variation. The results obtained showed that the equilibrium monolayer sorption capacity, qm, of the MMOL for CU (II) ions decreased (78.45 - 38.66 mg g-1) with an increase in sorbent dosage. The result obtained from pH optimization showed that CU(II) ions removal increases with increase in CU(II) ions solution pH.},
 year = {2018}
}

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TY  - JOUR
T1  - Copper (11) Ions Biosorption from Aqueous Solution Using Modified Moringa Oleiferal Leaves (MMOL)
AU  - Adebayo Oluwafemi Lawrence
AU  - Kenni Amoke Monisola
AU  - Oyetunde Julius Gbenga
AU  - Jegede Rufus Oluwafemi
AU  - Ajayi Margret Grace
Y1  - 2018/06/01
PY  - 2018
N1  - https://doi.org/10.11648/j.ajpc.20180702.11
DO  - 10.11648/j.ajpc.20180702.11
T2  - American Journal of Physical Chemistry
JF  - American Journal of Physical Chemistry
JO  - American Journal of Physical Chemistry
SP  - 12
EP  - 18
PB  - Science Publishing Group
SN  - 2327-2449
UR  - https://doi.org/10.11648/j.ajpc.20180702.11
AB  - The present research work demonstrated the ability of MMOL in removing Copper (II) ions from an aqueous solution. The modified (MMOL) and unmodified moringaoleifera (UMOL) was characterized based on PZC and surface area. Isotherm experiments were conducted and the data obtained were fitted to Langmuir and Freundlich isotherm equations. The Freundlich equation gave the best description of the sorption process and the maximum saturated monolayer sorption capacity of the MMOL for CU (II) ions was 78.45 mg g-1. The kinetics of the sorption process was studied by varying the initial CU (II) ions concentrations and the result obtained was analyzed by using pseudo-first-order and pseudo-second-order kinetic models. The pseudo second-order kinetic model was found to fit the experimental data for the entire sorption period with high coefficient of determination (r2). The effects of MMOL dose were studied using batch sorption system. The linear form of the Langmuir equation was used to analyze the data obtained when the sorbent dosage was optimized by method of continuous variation. The results obtained showed that the equilibrium monolayer sorption capacity, qm, of the MMOL for CU (II) ions decreased (78.45 - 38.66 mg g-1) with an increase in sorbent dosage. The result obtained from pH optimization showed that CU(II) ions removal increases with increase in CU(II) ions solution pH.
VL  - 7
IS  - 2
ER  -

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Author Information

Adebayo Oluwafemi Lawrence

Department of Chemistry, College of Education, Ikere, Ekiti State, Nigeria
Kenni Amoke Monisola

Department of Chemistry, College of Education, Ikere, Ekiti State, Nigeria
Oyetunde Julius Gbenga

Department of Chemistry, College of Education, Ikere, Ekiti State, Nigeria
Jegede Rufus Oluwafemi

Department of Chemistry, College of Education, Ikere, Ekiti State, Nigeria
Ajayi Margret Grace

Department of Chemistry, College of Education, Ikere, Ekiti State, Nigeria

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APA Style

Adebayo Oluwafemi Lawrence, Kenni Amoke Monisola, Oyetunde Julius Gbenga, Jegede Rufus Oluwafemi, Ajayi Margret Grace. (2018). Copper (11) Ions Biosorption from Aqueous Solution Using Modified Moringa Oleiferal Leaves (MMOL). American Journal of Physical Chemistry, 7(2), 12-18. https://doi.org/10.11648/j.ajpc.20180702.11

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ACS Style

Adebayo Oluwafemi Lawrence; Kenni Amoke Monisola; Oyetunde Julius Gbenga; Jegede Rufus Oluwafemi; Ajayi Margret Grace. Copper (11) Ions Biosorption from Aqueous Solution Using Modified Moringa Oleiferal Leaves (MMOL). Am. J. Phys. Chem. 2018, 7(2), 12-18. doi: 10.11648/j.ajpc.20180702.11

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AMA Style

Adebayo Oluwafemi Lawrence, Kenni Amoke Monisola, Oyetunde Julius Gbenga, Jegede Rufus Oluwafemi, Ajayi Margret Grace. Copper (11) Ions Biosorption from Aqueous Solution Using Modified Moringa Oleiferal Leaves (MMOL). Am J Phys Chem. 2018;7(2):12-18. doi: 10.11648/j.ajpc.20180702.11

Copy | Download

@article{10.11648/j.ajpc.20180702.11,
  author = {Adebayo Oluwafemi Lawrence and Kenni Amoke Monisola and Oyetunde Julius Gbenga and Jegede Rufus Oluwafemi and Ajayi Margret Grace},
  title = {Copper (11) Ions Biosorption from Aqueous Solution Using Modified Moringa Oleiferal Leaves (MMOL)},
  journal = {American Journal of Physical Chemistry},
  volume = {7},
  number = {2},
  pages = {12-18},
  doi = {10.11648/j.ajpc.20180702.11},
  url = {https://doi.org/10.11648/j.ajpc.20180702.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpc.20180702.11},
  abstract = {The present research work demonstrated the ability of MMOL in removing Copper (II) ions from an aqueous solution. The modified (MMOL) and unmodified moringaoleifera (UMOL) was characterized based on PZC and surface area. Isotherm experiments were conducted and the data obtained were fitted to Langmuir and Freundlich isotherm equations. The Freundlich equation gave the best description of the sorption process and the maximum saturated monolayer sorption capacity of the MMOL for CU (II) ions was 78.45 mg g-1. The kinetics of the sorption process was studied by varying the initial CU (II) ions concentrations and the result obtained was analyzed by using pseudo-first-order and pseudo-second-order kinetic models. The pseudo second-order kinetic model was found to fit the experimental data for the entire sorption period with high coefficient of determination (r2). The effects of MMOL dose were studied using batch sorption system. The linear form of the Langmuir equation was used to analyze the data obtained when the sorbent dosage was optimized by method of continuous variation. The results obtained showed that the equilibrium monolayer sorption capacity, qm, of the MMOL for CU (II) ions decreased (78.45 - 38.66 mg g-1) with an increase in sorbent dosage. The result obtained from pH optimization showed that CU(II) ions removal increases with increase in CU(II) ions solution pH.},
 year = {2018}
}

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TY  - JOUR
T1  - Copper (11) Ions Biosorption from Aqueous Solution Using Modified Moringa Oleiferal Leaves (MMOL)
AU  - Adebayo Oluwafemi Lawrence
AU  - Kenni Amoke Monisola
AU  - Oyetunde Julius Gbenga
AU  - Jegede Rufus Oluwafemi
AU  - Ajayi Margret Grace
Y1  - 2018/06/01
PY  - 2018
N1  - https://doi.org/10.11648/j.ajpc.20180702.11
DO  - 10.11648/j.ajpc.20180702.11
T2  - American Journal of Physical Chemistry
JF  - American Journal of Physical Chemistry
JO  - American Journal of Physical Chemistry
SP  - 12
EP  - 18
PB  - Science Publishing Group
SN  - 2327-2449
UR  - https://doi.org/10.11648/j.ajpc.20180702.11
AB  - The present research work demonstrated the ability of MMOL in removing Copper (II) ions from an aqueous solution. The modified (MMOL) and unmodified moringaoleifera (UMOL) was characterized based on PZC and surface area. Isotherm experiments were conducted and the data obtained were fitted to Langmuir and Freundlich isotherm equations. The Freundlich equation gave the best description of the sorption process and the maximum saturated monolayer sorption capacity of the MMOL for CU (II) ions was 78.45 mg g-1. The kinetics of the sorption process was studied by varying the initial CU (II) ions concentrations and the result obtained was analyzed by using pseudo-first-order and pseudo-second-order kinetic models. The pseudo second-order kinetic model was found to fit the experimental data for the entire sorption period with high coefficient of determination (r2). The effects of MMOL dose were studied using batch sorption system. The linear form of the Langmuir equation was used to analyze the data obtained when the sorbent dosage was optimized by method of continuous variation. The results obtained showed that the equilibrium monolayer sorption capacity, qm, of the MMOL for CU (II) ions decreased (78.45 - 38.66 mg g-1) with an increase in sorbent dosage. The result obtained from pH optimization showed that CU(II) ions removal increases with increase in CU(II) ions solution pH.
VL  - 7
IS  - 2
ER  -

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