Volumetric and Ultrasonic Study of Mixtures of Benzyl Alcohol with 1-Propanol, 2-Propanol, and 1,2-Propandiol, 1,3-Propandiol and T-butanol

Fatemeh Fadaei Nobandegani; Abouzar Roeintan

doi:doi:10.11648/j.ajma.20190704.12

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Volumetric and Ultrasonic Study of Mixtures of Benzyl Alcohol with 1-Propanol, 2-Propanol, and 1,2-Propandiol, 1,3-Propandiol and T-butanol

Fatemeh Fadaei Nobandegani, Abouzar Roeintan

Published in American Journal of Mechanics and Applications (Volume 7, Issue 4)

Received: 22 June 2019 Accepted: 15 July 2019 Published: 8 January 2020

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Abstract

Densities and speeds of sound for five binary mixtures of benzylalcohol with 1,3-propandiol, 1- propanol, 2- propanol, 1,2-propandiol and phenylethnol were measured over the entire range of composition and at five temperatures from 298.15K to 323.15K at 5K interval and atmospheric pressure using a vibrating u-tube densimeter (DSA 5000). Besides, the densities for pure compounds in the above-mentioned temperature range were measured. The experimental densities were used to calculate the excess molar volumes, isentropic compressibility changes, the excess thermal expansion coefficients, and the excess partial molar volumes at infinite dilution, The results have been used to discuss the nature and strength of intermolecular interactions in these mixtures. The calculated excess and deviations quantities are correlated with the third-order Redlich–Kister equation. As a final work we modeled the experiment results by using TM and PR EOSs. This is clear that the results with TM EOS are more acceptable than PR EOS. TM and PR EOS can successfully predict density and excess molar volume. And are unable to predict speed of sound.

Published in	American Journal of Mechanics and Applications (Volume 7, Issue 4)
DOI	10.11648/j.ajma.20190704.12
Page(s)	88-100
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2020. Published by Science Publishing Group

Keywords

Alcohols, Binary Mixtures, Excess Properties, Density, Modeling, Speed of Sound

References

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Fatemeh Fadaei Nobandegani, Abouzar Roeintan. (2020). Volumetric and Ultrasonic Study of Mixtures of Benzyl Alcohol with 1-Propanol, 2-Propanol, and 1,2-Propandiol, 1,3-Propandiol and T-butanol. American Journal of Mechanics and Applications, 7(4), 88-100. https://doi.org/10.11648/j.ajma.20190704.12

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Fatemeh Fadaei Nobandegani; Abouzar Roeintan. Volumetric and Ultrasonic Study of Mixtures of Benzyl Alcohol with 1-Propanol, 2-Propanol, and 1,2-Propandiol, 1,3-Propandiol and T-butanol. Am. J. Mech. Appl. 2020, 7(4), 88-100. doi: 10.11648/j.ajma.20190704.12

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AMA Style

Fatemeh Fadaei Nobandegani, Abouzar Roeintan. Volumetric and Ultrasonic Study of Mixtures of Benzyl Alcohol with 1-Propanol, 2-Propanol, and 1,2-Propandiol, 1,3-Propandiol and T-butanol. Am J Mech Appl. 2020;7(4):88-100. doi: 10.11648/j.ajma.20190704.12

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@article{10.11648/j.ajma.20190704.12,
  author = {Fatemeh Fadaei Nobandegani and Abouzar Roeintan},
  title = {Volumetric and Ultrasonic Study of Mixtures of Benzyl Alcohol with 1-Propanol, 2-Propanol, and 1,2-Propandiol, 1,3-Propandiol and T-butanol},
  journal = {American Journal of Mechanics and Applications},
  volume = {7},
  number = {4},
  pages = {88-100},
  doi = {10.11648/j.ajma.20190704.12},
  url = {https://doi.org/10.11648/j.ajma.20190704.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajma.20190704.12},
  abstract = {Densities and speeds of sound for five binary mixtures of benzylalcohol with 1,3-propandiol, 1- propanol, 2- propanol, 1,2-propandiol and phenylethnol were measured over the entire range of composition and at five temperatures from 298.15K to 323.15K at 5K interval and atmospheric pressure using a vibrating u-tube densimeter (DSA 5000). Besides, the densities for pure compounds in the above-mentioned temperature range were measured. The experimental densities were used to calculate the excess molar volumes, isentropic compressibility changes, the excess thermal expansion coefficients, and the excess partial molar volumes at infinite dilution, The results have been used to discuss the nature and strength of intermolecular interactions in these mixtures. The calculated excess and deviations quantities are correlated with the third-order Redlich–Kister equation. As a final work we modeled the experiment results by using TM and PR EOSs. This is clear that the results with TM EOS are more acceptable than PR EOS. TM and PR EOS can successfully predict density and excess molar volume. And are unable to predict speed of sound.},
 year = {2020}
}

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TY  - JOUR
T1  - Volumetric and Ultrasonic Study of Mixtures of Benzyl Alcohol with 1-Propanol, 2-Propanol, and 1,2-Propandiol, 1,3-Propandiol and T-butanol
AU  - Fatemeh Fadaei Nobandegani
AU  - Abouzar Roeintan
Y1  - 2020/01/08
PY  - 2020
N1  - https://doi.org/10.11648/j.ajma.20190704.12
DO  - 10.11648/j.ajma.20190704.12
T2  - American Journal of Mechanics and Applications
JF  - American Journal of Mechanics and Applications
JO  - American Journal of Mechanics and Applications
SP  - 88
EP  - 100
PB  - Science Publishing Group
SN  - 2376-6131
UR  - https://doi.org/10.11648/j.ajma.20190704.12
AB  - Densities and speeds of sound for five binary mixtures of benzylalcohol with 1,3-propandiol, 1- propanol, 2- propanol, 1,2-propandiol and phenylethnol were measured over the entire range of composition and at five temperatures from 298.15K to 323.15K at 5K interval and atmospheric pressure using a vibrating u-tube densimeter (DSA 5000). Besides, the densities for pure compounds in the above-mentioned temperature range were measured. The experimental densities were used to calculate the excess molar volumes, isentropic compressibility changes, the excess thermal expansion coefficients, and the excess partial molar volumes at infinite dilution, The results have been used to discuss the nature and strength of intermolecular interactions in these mixtures. The calculated excess and deviations quantities are correlated with the third-order Redlich–Kister equation. As a final work we modeled the experiment results by using TM and PR EOSs. This is clear that the results with TM EOS are more acceptable than PR EOS. TM and PR EOS can successfully predict density and excess molar volume. And are unable to predict speed of sound.
VL  - 7
IS  - 4
ER  -

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Author Information

Fatemeh Fadaei Nobandegani

Department of Food Science and Thecnology, Fasa University, Fasa, Iran
Abouzar Roeintan

Department of Chemistry, Emam Hossein University, Tehran, Iran

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APA Style

Fatemeh Fadaei Nobandegani, Abouzar Roeintan. (2020). Volumetric and Ultrasonic Study of Mixtures of Benzyl Alcohol with 1-Propanol, 2-Propanol, and 1,2-Propandiol, 1,3-Propandiol and T-butanol. American Journal of Mechanics and Applications, 7(4), 88-100. https://doi.org/10.11648/j.ajma.20190704.12

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ACS Style

Fatemeh Fadaei Nobandegani; Abouzar Roeintan. Volumetric and Ultrasonic Study of Mixtures of Benzyl Alcohol with 1-Propanol, 2-Propanol, and 1,2-Propandiol, 1,3-Propandiol and T-butanol. Am. J. Mech. Appl. 2020, 7(4), 88-100. doi: 10.11648/j.ajma.20190704.12

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AMA Style

Fatemeh Fadaei Nobandegani, Abouzar Roeintan. Volumetric and Ultrasonic Study of Mixtures of Benzyl Alcohol with 1-Propanol, 2-Propanol, and 1,2-Propandiol, 1,3-Propandiol and T-butanol. Am J Mech Appl. 2020;7(4):88-100. doi: 10.11648/j.ajma.20190704.12

Copy | Download

@article{10.11648/j.ajma.20190704.12,
  author = {Fatemeh Fadaei Nobandegani and Abouzar Roeintan},
  title = {Volumetric and Ultrasonic Study of Mixtures of Benzyl Alcohol with 1-Propanol, 2-Propanol, and 1,2-Propandiol, 1,3-Propandiol and T-butanol},
  journal = {American Journal of Mechanics and Applications},
  volume = {7},
  number = {4},
  pages = {88-100},
  doi = {10.11648/j.ajma.20190704.12},
  url = {https://doi.org/10.11648/j.ajma.20190704.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajma.20190704.12},
  abstract = {Densities and speeds of sound for five binary mixtures of benzylalcohol with 1,3-propandiol, 1- propanol, 2- propanol, 1,2-propandiol and phenylethnol were measured over the entire range of composition and at five temperatures from 298.15K to 323.15K at 5K interval and atmospheric pressure using a vibrating u-tube densimeter (DSA 5000). Besides, the densities for pure compounds in the above-mentioned temperature range were measured. The experimental densities were used to calculate the excess molar volumes, isentropic compressibility changes, the excess thermal expansion coefficients, and the excess partial molar volumes at infinite dilution, The results have been used to discuss the nature and strength of intermolecular interactions in these mixtures. The calculated excess and deviations quantities are correlated with the third-order Redlich–Kister equation. As a final work we modeled the experiment results by using TM and PR EOSs. This is clear that the results with TM EOS are more acceptable than PR EOS. TM and PR EOS can successfully predict density and excess molar volume. And are unable to predict speed of sound.},
 year = {2020}
}

Copy | Download

TY  - JOUR
T1  - Volumetric and Ultrasonic Study of Mixtures of Benzyl Alcohol with 1-Propanol, 2-Propanol, and 1,2-Propandiol, 1,3-Propandiol and T-butanol
AU  - Fatemeh Fadaei Nobandegani
AU  - Abouzar Roeintan
Y1  - 2020/01/08
PY  - 2020
N1  - https://doi.org/10.11648/j.ajma.20190704.12
DO  - 10.11648/j.ajma.20190704.12
T2  - American Journal of Mechanics and Applications
JF  - American Journal of Mechanics and Applications
JO  - American Journal of Mechanics and Applications
SP  - 88
EP  - 100
PB  - Science Publishing Group
SN  - 2376-6131
UR  - https://doi.org/10.11648/j.ajma.20190704.12
AB  - Densities and speeds of sound for five binary mixtures of benzylalcohol with 1,3-propandiol, 1- propanol, 2- propanol, 1,2-propandiol and phenylethnol were measured over the entire range of composition and at five temperatures from 298.15K to 323.15K at 5K interval and atmospheric pressure using a vibrating u-tube densimeter (DSA 5000). Besides, the densities for pure compounds in the above-mentioned temperature range were measured. The experimental densities were used to calculate the excess molar volumes, isentropic compressibility changes, the excess thermal expansion coefficients, and the excess partial molar volumes at infinite dilution, The results have been used to discuss the nature and strength of intermolecular interactions in these mixtures. The calculated excess and deviations quantities are correlated with the third-order Redlich–Kister equation. As a final work we modeled the experiment results by using TM and PR EOSs. This is clear that the results with TM EOS are more acceptable than PR EOS. TM and PR EOS can successfully predict density and excess molar volume. And are unable to predict speed of sound.
VL  - 7
IS  - 4
ER  -

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