Determination of Isotopic Composition and Concentration of Uranium and Boron by Thermal Ionization Mass Spectrometric Isotopic Dilution Technique

Hilal Shahab Wahab; Khalil Ibraheem Hussain

doi:doi:10.11648/j.ajac.20140202.11

| Peer-Reviewed

Determination of Isotopic Composition and Concentration of Uranium and Boron by Thermal Ionization Mass Spectrometric Isotopic Dilution Technique

Hilal Shahab Wahab, Khalil Ibraheem Hussain

Published in American Journal of Applied Chemistry (Volume 2, Issue 2)

Received: 13 March 2014 Accepted: 10 April 2014 Published: 20 April 2014

Views: Downloads:

Download PDF

Share This Article

Twitter
Linked In
Facebook

Abstract

In this study, the determination of isotopic composition and concentration of uranium and boron by mass spectrometric isotopic dilution have been performed .The isotopic composition was measured using thermal ionization mass spectrometer methodology employing U-233 and B-10 as spike isotope standards. The accuracy and reproducibility of the isotopic ratio and concentration measurements were evaluated

Published in	American Journal of Applied Chemistry (Volume 2, Issue 2)
DOI	10.11648/j.ajac.20140202.11
Page(s)	27-32
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2014. Published by Science Publishing Group

Keywords

Mass Spectrometry, Boron Isotopes, Uranium Isotopes, Isotope Dilution Technique

References

[1]	Y. J. Park, H. Y. Pyo, K. Song, B. C. Song, K. Y. Jee and W. H. Kim, Bull. Korean Chem. Soc., 27 (10) (2006) 1609-1612.
[2]	T. U. Probost, Fresenius Z. Anal. Chem. 364 (1999) 391.
[3]	P. W. May, K. N. Fox, N. A. Younes, C. M. Beardmore, Diamond and Related Materials 6 (1997) 450.
[4]	C. J. Park, Bull. Korean Chem. Soc. 23 (2002) 1541-1544.
[5]	A. Lamberty, V. Holland, A. Verbruggen, F. Hendrickx and P. Debievre, Fresenius Z. Anal. Chem. 332 (1988) 645-647.
[6]	R. M. Rao, A. R. Parab, K. S. Bhushan and S. K. Aggarwal, Microchim Acta 169 (2010) 227-231.
[7]	G. Menard, I. Vlastelic, D. A. Ionov, E. F. Rose-Koga, J. Piro and C. Pin, Chemical Geology 354 (2013) 139-149.
[8]	W. Arden and N. H. Gale, Anal. chem. 46 (1974) 687-691.
[9]	M. Haldimann, M. Baduraux, A. Eastgate, P. Froidevaux, S. O'Donova, D. Von Gunten and O. Zoller, J. Anal. At. Spectrom 16 (2001) 1364-1369.
[10]	A. G. Adriaens, J. D. Fassett, W. R. Kelly, D. S. Simons and F. C. Adams, Anal. Chem. 64 (1992) 2945-2950.
[11]	D. Vopalka and J. Cabical, Int. J. Mass Spec. and Ion Physics 48 (1983) 401-404.
[12]	V. J. Heinonen and R. J. Korhonen, J. Radioal. Chem. 64, No. 1-2 (1981) 65-72.
[13]	L. Koch, Radio Chim. Acta. 12 (1969) 16.
[14]	J. Krtil, F. Sus and J. Mensl, J. Radioanal. Chem. 28 (1975) 109-118.
[15]	F. Sus and J. Krtil, J. Radioanal. Chem. 15 (1979) 143-151.
[16]	E. J. Spitzer and J. R. Sites, "Isotopic mass spectrometry of the elements'' USAEC, Rept., ORNL-3528.
[17]	M. W. Lerner "The Analysis of Elemental Boron", TID-25910 (1970).
[18]	R. O. Inlow and J. M. scarborough, Anal. Chem. 48 (1976) 1357.
[19]	A. Henrion, Fres. J. Anal.Chem. 350 (1994) 657-658.
[20]	J.Tolgyessy, T. Braun and M. Kyrs,"Isotope Dilution Analysis" pergamon press, Oxford (1972)
[21]	W. Beyrich and E. Drosselmyer, “The Interlaboratory Experiment” IDA-72 on M.S.I.D.A.," kfk-1905/1 and Kfk-1905/11 (July 1975).
[22]	H. O. Finely and E. E. Luang, USAEC Rept., NBL-170 (1961) "Mass Spectrometric Determination of Boron Isotopic Abundance in the Near Normal Range

Cite This Article

Plain Text BibTeX RIS

APA Style

Hilal Shahab Wahab, Khalil Ibraheem Hussain. (2014). Determination of Isotopic Composition and Concentration of Uranium and Boron by Thermal Ionization Mass Spectrometric Isotopic Dilution Technique. American Journal of Applied Chemistry, 2(2), 27-32. https://doi.org/10.11648/j.ajac.20140202.11

Copy | Download

ACS Style

Hilal Shahab Wahab; Khalil Ibraheem Hussain. Determination of Isotopic Composition and Concentration of Uranium and Boron by Thermal Ionization Mass Spectrometric Isotopic Dilution Technique. Am. J. Appl. Chem. 2014, 2(2), 27-32. doi: 10.11648/j.ajac.20140202.11

Copy | Download

AMA Style

Hilal Shahab Wahab, Khalil Ibraheem Hussain. Determination of Isotopic Composition and Concentration of Uranium and Boron by Thermal Ionization Mass Spectrometric Isotopic Dilution Technique. Am J Appl Chem. 2014;2(2):27-32. doi: 10.11648/j.ajac.20140202.11

Copy | Download

@article{10.11648/j.ajac.20140202.11,
  author = {Hilal Shahab Wahab and Khalil Ibraheem Hussain},
  title = {Determination of Isotopic Composition and Concentration of Uranium and Boron by Thermal Ionization Mass Spectrometric Isotopic Dilution Technique},
  journal = {American Journal of Applied Chemistry},
  volume = {2},
  number = {2},
  pages = {27-32},
  doi = {10.11648/j.ajac.20140202.11},
  url = {https://doi.org/10.11648/j.ajac.20140202.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20140202.11},
  abstract = {In this study, the determination of isotopic composition and concentration of uranium and boron by mass spectrometric isotopic dilution have been performed .The isotopic composition was measured using thermal ionization mass spectrometer methodology employing U-233 and B-10 as spike isotope standards. The accuracy and reproducibility of the isotopic ratio and concentration measurements were evaluated},
 year = {2014}
}

Copy | Download

TY  - JOUR
T1  - Determination of Isotopic Composition and Concentration of Uranium and Boron by Thermal Ionization Mass Spectrometric Isotopic Dilution Technique
AU  - Hilal Shahab Wahab
AU  - Khalil Ibraheem Hussain
Y1  - 2014/04/20
PY  - 2014
N1  - https://doi.org/10.11648/j.ajac.20140202.11
DO  - 10.11648/j.ajac.20140202.11
T2  - American Journal of Applied Chemistry
JF  - American Journal of Applied Chemistry
JO  - American Journal of Applied Chemistry
SP  - 27
EP  - 32
PB  - Science Publishing Group
SN  - 2330-8745
UR  - https://doi.org/10.11648/j.ajac.20140202.11
AB  - In this study, the determination of isotopic composition and concentration of uranium and boron by mass spectrometric isotopic dilution have been performed .The isotopic composition was measured using thermal ionization mass spectrometer methodology employing U-233 and B-10 as spike isotope standards. The accuracy and reproducibility of the isotopic ratio and concentration measurements were evaluated
VL  - 2
IS  - 2
ER  -

Copy | Download

Author Information

Hilal Shahab Wahab

Department of chemistry, College of Science, Al-Nahrain University, Al-Jadriya, Baghdad, Iraq
Khalil Ibraheem Hussain

Department of chemistry, College of Education - Ibn Al-Haitham, University of Baghdad, Al-Aadhamiya, Baghdad, Iraq

Download PDF

Sections

Plain Text BibTeX RIS

APA Style

Hilal Shahab Wahab, Khalil Ibraheem Hussain. (2014). Determination of Isotopic Composition and Concentration of Uranium and Boron by Thermal Ionization Mass Spectrometric Isotopic Dilution Technique. American Journal of Applied Chemistry, 2(2), 27-32. https://doi.org/10.11648/j.ajac.20140202.11

Copy | Download

ACS Style

Hilal Shahab Wahab; Khalil Ibraheem Hussain. Determination of Isotopic Composition and Concentration of Uranium and Boron by Thermal Ionization Mass Spectrometric Isotopic Dilution Technique. Am. J. Appl. Chem. 2014, 2(2), 27-32. doi: 10.11648/j.ajac.20140202.11

Copy | Download

AMA Style

Hilal Shahab Wahab, Khalil Ibraheem Hussain. Determination of Isotopic Composition and Concentration of Uranium and Boron by Thermal Ionization Mass Spectrometric Isotopic Dilution Technique. Am J Appl Chem. 2014;2(2):27-32. doi: 10.11648/j.ajac.20140202.11

Copy | Download

@article{10.11648/j.ajac.20140202.11,
  author = {Hilal Shahab Wahab and Khalil Ibraheem Hussain},
  title = {Determination of Isotopic Composition and Concentration of Uranium and Boron by Thermal Ionization Mass Spectrometric Isotopic Dilution Technique},
  journal = {American Journal of Applied Chemistry},
  volume = {2},
  number = {2},
  pages = {27-32},
  doi = {10.11648/j.ajac.20140202.11},
  url = {https://doi.org/10.11648/j.ajac.20140202.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20140202.11},
  abstract = {In this study, the determination of isotopic composition and concentration of uranium and boron by mass spectrometric isotopic dilution have been performed .The isotopic composition was measured using thermal ionization mass spectrometer methodology employing U-233 and B-10 as spike isotope standards. The accuracy and reproducibility of the isotopic ratio and concentration measurements were evaluated},
 year = {2014}
}

Copy | Download

TY  - JOUR
T1  - Determination of Isotopic Composition and Concentration of Uranium and Boron by Thermal Ionization Mass Spectrometric Isotopic Dilution Technique
AU  - Hilal Shahab Wahab
AU  - Khalil Ibraheem Hussain
Y1  - 2014/04/20
PY  - 2014
N1  - https://doi.org/10.11648/j.ajac.20140202.11
DO  - 10.11648/j.ajac.20140202.11
T2  - American Journal of Applied Chemistry
JF  - American Journal of Applied Chemistry
JO  - American Journal of Applied Chemistry
SP  - 27
EP  - 32
PB  - Science Publishing Group
SN  - 2330-8745
UR  - https://doi.org/10.11648/j.ajac.20140202.11
AB  - In this study, the determination of isotopic composition and concentration of uranium and boron by mass spectrometric isotopic dilution have been performed .The isotopic composition was measured using thermal ionization mass spectrometer methodology employing U-233 and B-10 as spike isotope standards. The accuracy and reproducibility of the isotopic ratio and concentration measurements were evaluated
VL  - 2
IS  - 2
ER  -

Copy | Download