Synthesis and Characterization of Lanthanide Complexes of N6 – Macrocyclic Schiff Base

KHALIL KHALAF ABID

doi:doi:10.11648/j.ajac.20130104.11

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Synthesis and Characterization of Lanthanide Complexes of N6 – Macrocyclic Schiff Base

KHALIL KHALAF ABID

Published in American Journal of Applied Chemistry (Volume 1, Issue 4)

Received: 24 September 2013 Published: 30 October 2013

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Abstract

A new macrocyclic Schiff base complexes were prepared in the presence of lanthanide metal ion[La(III), Ce(III) and Gd(III)] by the reaction of 2,6 – diamino pyridine, benzoyl aceton and metal ion as template effect in the molar ratio of 2: 2: 1 respectively. The lanthanide metal complexes were characterized and investigated by using; 1HNMR, FTIR, UV/Visible spectroscopy, Elemental analysis (C.H.N.), Magnetic susceptibility and Molar conductivity measurements. The lanthanide metal ions coordinated to six nitrogen atoms of the ligand and three chloride ions to complete geometry of nine coordination complexes.

Published in	American Journal of Applied Chemistry (Volume 1, Issue 4)
DOI	10.11648/j.ajac.20130104.11
Page(s)	49-52
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2013. Published by Science Publishing Group

Keywords

Macrocyclic, Schiff Bases, Lanthanide Complexes, Template Synthesis

References

[1]	P. A. Vigato and S. Tamburini; Coord. Chem. Rev., 248 (2004) 1717.
[2]	P. A. Vigato, S. Tamburini and L. Bertolo; Coord. Chem. Rev., 251 (2004) 1311.
[3]	W. Radecka-Paryzek, V. Patroniak and J. Lisowski; Coord. Chem. Rev., 249 (2005) 2156.
[4]	H. Karsilayan, I. Hemmila, H. Takalo, A. Toivonen, K. Pettersson, T. Lovgren and V-M. Mukkala; Bioconjugate Chem., (1997) 871.
[5]	M. Li and P. Selvin; Bioconjugate Chem., 8 (1997) 127.
[6]	R. B. Lauffer; Chem. Rev., 87 (1987) 901.
[7]	S. Aime, M. Botta, M. Fasano and E. Terreno; Acc. Chem. Res., 32 (1999) 941.
[8]	P. H. Smith, J. R. Brainard, D. E. Morris, G. D. Jarvinen and R. R. Ryan; J. Am. Chem. Soc., 111 (1989) 7437.
[9]	K. Kolasa, A. Sharma and J. R. Morrow; Inorg. Chem., 32 (1993) 3983.
[10]	L. L. Chappell, D. A. Voss Jr., W. DeW. Horrocks Jr. and J. R. Morrow; Inorg. Chem., 37 (1998) 3989.
[11]	S. Amin, D. A. Voss Jr, W. DeW. Horrocks Jr. and J. R. Morrow; Inorg. Chem., 35 (1996) 7466.
[12]	J. R. Morrow;" Metal Ions in Biological Systems" (1996) 33H, Sigel (Ed.) Dekker, New York, pp. 561–591.
[13]	A. De Mesmaeker, R. Haner, R. P. Martin, H. E. Moser; Acc. Chem. Res.,28 (1995) 366.
[14]	D. Magda, M. Wright, S. Crofts, A. Lin and J. L. Sessler; J. Am. Chem. Soc.,119 (1997) 6947.
[15]	J. R. Morrow, L. A. Buttrey, V. M. Shelton and K. A. Berback; J. Am. Chem. Soc., 114 (1992) 1903.
[16]	J. Lisowski and P. Starynowicz; Polyhedron,18 (1998) 443.
[17]	E. Spodine, Y. Moreno, M.T. Garland,O. Pena and R. Baggio; Inorg. Chim. Acta,30 (2000) 957
[18]	S. Chandrai, M. Tyagi and S. Agrawalj; Serb. Chem. Soc. 75 (7) (2010) 935
[19]	S. S. Nivasan and P. Athappan ; Transition Met. Chemistry, 26 (2001) 588
[20]	C. Lodeiro, R. Basitida, E. Bertolo, A. Macias and R. Rodriguez ; Transition Met. Chemistry, 28 (2003) 388.
[21]	V. B. Rana, J. N. Gurtu and M. P. Teotia; Indian J. Chem., 19A (1980) 133.
[22]	P. K. Sasmal , S. Saha , R. Majumdar and R. Dighe ; Inorg. Chem., 49(3) (2010) 849.
[23]	M. R. Maurya, A. Kumar, A. R. Bhat, A. R. Azam, A. Bader and D. Rehder ; Inorg. Chem., 45(3) (2006) 1260.
[24]	T. Szczurek, and M. Schlesinger" Rare Earth Spectroscopy" World Scientiﬁc, Singapore (1985) p309
[25]	M. H. V. Werts ; Science Progress, 88 (2005) 101.
[26]	N. Greenwood and A. Earnshaw;"Chemistry of the Elements " (1997) p 1242, 2ndedition, Butterworth – Heinmann. ISBN 0080379419.

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KHALIL KHALAF ABID. (2013). Synthesis and Characterization of Lanthanide Complexes of N6 – Macrocyclic Schiff Base. American Journal of Applied Chemistry, 1(4), 49-52. https://doi.org/10.11648/j.ajac.20130104.11

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KHALIL KHALAF ABID. Synthesis and Characterization of Lanthanide Complexes of N6 – Macrocyclic Schiff Base. Am. J. Appl. Chem. 2013, 1(4), 49-52. doi: 10.11648/j.ajac.20130104.11

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AMA Style

KHALIL KHALAF ABID. Synthesis and Characterization of Lanthanide Complexes of N6 – Macrocyclic Schiff Base. Am J Appl Chem. 2013;1(4):49-52. doi: 10.11648/j.ajac.20130104.11

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@article{10.11648/j.ajac.20130104.11,
  author = {KHALIL KHALAF ABID},
  title = {Synthesis and Characterization of Lanthanide Complexes of N6 – Macrocyclic Schiff Base},
  journal = {American Journal of Applied Chemistry},
  volume = {1},
  number = {4},
  pages = {49-52},
  doi = {10.11648/j.ajac.20130104.11},
  url = {https://doi.org/10.11648/j.ajac.20130104.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20130104.11},
  abstract = {A new macrocyclic Schiff base complexes were prepared in the presence of lanthanide metal ion[La(III), Ce(III) and Gd(III)] by the reaction of 2,6 – diamino pyridine,  benzoyl aceton and metal ion as template effect in the molar ratio of  2: 2: 1 respectively. The lanthanide metal complexes were characterized and investigated by using; 1HNMR, FTIR, UV/Visible spectroscopy, Elemental analysis (C.H.N.), Magnetic susceptibility and Molar conductivity measurements. The lanthanide metal ions coordinated to six nitrogen atoms of the ligand and three chloride ions to complete geometry of nine coordination complexes.},
 year = {2013}
}

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TY  - JOUR
T1  - Synthesis and Characterization of Lanthanide Complexes of N6 – Macrocyclic Schiff Base
AU  - KHALIL KHALAF ABID
Y1  - 2013/10/30
PY  - 2013
N1  - https://doi.org/10.11648/j.ajac.20130104.11
DO  - 10.11648/j.ajac.20130104.11
T2  - American Journal of Applied Chemistry
JF  - American Journal of Applied Chemistry
JO  - American Journal of Applied Chemistry
SP  - 49
EP  - 52
PB  - Science Publishing Group
SN  - 2330-8745
UR  - https://doi.org/10.11648/j.ajac.20130104.11
AB  - A new macrocyclic Schiff base complexes were prepared in the presence of lanthanide metal ion[La(III), Ce(III) and Gd(III)] by the reaction of 2,6 – diamino pyridine,  benzoyl aceton and metal ion as template effect in the molar ratio of  2: 2: 1 respectively. The lanthanide metal complexes were characterized and investigated by using; 1HNMR, FTIR, UV/Visible spectroscopy, Elemental analysis (C.H.N.), Magnetic susceptibility and Molar conductivity measurements. The lanthanide metal ions coordinated to six nitrogen atoms of the ligand and three chloride ions to complete geometry of nine coordination complexes.
VL  - 1
IS  - 4
ER  -

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Author Information

KHALIL KHALAF ABID

Department of Chemistry, College of Science, Al – Mustanseriyah University, 10053 Baghdad Iraq

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KHALIL KHALAF ABID. (2013). Synthesis and Characterization of Lanthanide Complexes of N6 – Macrocyclic Schiff Base. American Journal of Applied Chemistry, 1(4), 49-52. https://doi.org/10.11648/j.ajac.20130104.11

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ACS Style

KHALIL KHALAF ABID. Synthesis and Characterization of Lanthanide Complexes of N6 – Macrocyclic Schiff Base. Am. J. Appl. Chem. 2013, 1(4), 49-52. doi: 10.11648/j.ajac.20130104.11

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AMA Style

KHALIL KHALAF ABID. Synthesis and Characterization of Lanthanide Complexes of N6 – Macrocyclic Schiff Base. Am J Appl Chem. 2013;1(4):49-52. doi: 10.11648/j.ajac.20130104.11

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@article{10.11648/j.ajac.20130104.11,
  author = {KHALIL KHALAF ABID},
  title = {Synthesis and Characterization of Lanthanide Complexes of N6 – Macrocyclic Schiff Base},
  journal = {American Journal of Applied Chemistry},
  volume = {1},
  number = {4},
  pages = {49-52},
  doi = {10.11648/j.ajac.20130104.11},
  url = {https://doi.org/10.11648/j.ajac.20130104.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20130104.11},
  abstract = {A new macrocyclic Schiff base complexes were prepared in the presence of lanthanide metal ion[La(III), Ce(III) and Gd(III)] by the reaction of 2,6 – diamino pyridine,  benzoyl aceton and metal ion as template effect in the molar ratio of  2: 2: 1 respectively. The lanthanide metal complexes were characterized and investigated by using; 1HNMR, FTIR, UV/Visible spectroscopy, Elemental analysis (C.H.N.), Magnetic susceptibility and Molar conductivity measurements. The lanthanide metal ions coordinated to six nitrogen atoms of the ligand and three chloride ions to complete geometry of nine coordination complexes.},
 year = {2013}
}

Copy | Download

TY  - JOUR
T1  - Synthesis and Characterization of Lanthanide Complexes of N6 – Macrocyclic Schiff Base
AU  - KHALIL KHALAF ABID
Y1  - 2013/10/30
PY  - 2013
N1  - https://doi.org/10.11648/j.ajac.20130104.11
DO  - 10.11648/j.ajac.20130104.11
T2  - American Journal of Applied Chemistry
JF  - American Journal of Applied Chemistry
JO  - American Journal of Applied Chemistry
SP  - 49
EP  - 52
PB  - Science Publishing Group
SN  - 2330-8745
UR  - https://doi.org/10.11648/j.ajac.20130104.11
AB  - A new macrocyclic Schiff base complexes were prepared in the presence of lanthanide metal ion[La(III), Ce(III) and Gd(III)] by the reaction of 2,6 – diamino pyridine,  benzoyl aceton and metal ion as template effect in the molar ratio of  2: 2: 1 respectively. The lanthanide metal complexes were characterized and investigated by using; 1HNMR, FTIR, UV/Visible spectroscopy, Elemental analysis (C.H.N.), Magnetic susceptibility and Molar conductivity measurements. The lanthanide metal ions coordinated to six nitrogen atoms of the ligand and three chloride ions to complete geometry of nine coordination complexes.
VL  - 1
IS  - 4
ER  -

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