Thermophysical Properties and X-Ray Structure Investigations of Polyurethane Ureas, Containing Folate Derivative of Ferrocene

Liudmyla Kulyk; Rita Rozhnova; Iryna Gladyr; Nataliia Galatenko

doi:doi:10.11648/j.ajpc.20170604.13

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Thermophysical Properties and X-Ray Structure Investigations of Polyurethane Ureas, Containing Folate Derivative of Ferrocene

Liudmyla Kulyk, Rita Rozhnova, Iryna Gladyr, Nataliia Galatenko

Published in American Journal of Physical Chemistry (Volume 6, Issue 4)

Received: 1 July 2017 Accepted: 19 July 2017 Published: 15 August 2017

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Abstract

Thermophysical properties of polyurethane ureas by thermogravimetry and differential scanning calorimetry were studied. It was shown, that investigated polyurethane ureas are heat-resistant up to 523 K. The structure of polyurethane ureas, containing folate derivative of ferrocene, by wide-angle and small angle X-ray method for different content of folate-derivative of ferrocene was investigated. Wide-angle X-ray diffraction data revealed that the introduction of 0.01 mole of folate derivative of ferrocene to the PUU structure leads to the change of period alternating arrangement of flexible and rigid blocks of PUU, significant degradation of heterogeneous structure, but does not cause changes in amorphous structure of the polymer.

Published in	American Journal of Physical Chemistry (Volume 6, Issue 4)
DOI	10.11648/j.ajpc.20170604.13
Page(s)	70-75
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2017. Published by Science Publishing Group

Keywords

Polyurethane Urea, Folate Derivative of Ferrocene, Folic Acid, X-Ray Method, Thermogravimetry, Differential Scanning Calorimetry

References

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[4]	Мakeeva L., Gladyr І, Rozhnova R., Galatenko N.: Polimernyj Journal, 2014, 36, № 2, 181.
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APA Style

Liudmyla Kulyk, Rita Rozhnova, Iryna Gladyr, Nataliia Galatenko. (2017). Thermophysical Properties and X-Ray Structure Investigations of Polyurethane Ureas, Containing Folate Derivative of Ferrocene. American Journal of Physical Chemistry, 6(4), 70-75. https://doi.org/10.11648/j.ajpc.20170604.13

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ACS Style

Liudmyla Kulyk; Rita Rozhnova; Iryna Gladyr; Nataliia Galatenko. Thermophysical Properties and X-Ray Structure Investigations of Polyurethane Ureas, Containing Folate Derivative of Ferrocene. Am. J. Phys. Chem. 2017, 6(4), 70-75. doi: 10.11648/j.ajpc.20170604.13

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AMA Style

Liudmyla Kulyk, Rita Rozhnova, Iryna Gladyr, Nataliia Galatenko. Thermophysical Properties and X-Ray Structure Investigations of Polyurethane Ureas, Containing Folate Derivative of Ferrocene. Am J Phys Chem. 2017;6(4):70-75. doi: 10.11648/j.ajpc.20170604.13

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@article{10.11648/j.ajpc.20170604.13,
  author = {Liudmyla Kulyk and Rita Rozhnova and Iryna Gladyr and Nataliia Galatenko},
  title = {Thermophysical Properties and X-Ray Structure Investigations of Polyurethane Ureas, Containing Folate Derivative of Ferrocene},
  journal = {American Journal of Physical Chemistry},
  volume = {6},
  number = {4},
  pages = {70-75},
  doi = {10.11648/j.ajpc.20170604.13},
  url = {https://doi.org/10.11648/j.ajpc.20170604.13},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpc.20170604.13},
  abstract = {Thermophysical properties of polyurethane ureas by thermogravimetry and differential scanning calorimetry were studied. It was shown, that investigated polyurethane ureas are heat-resistant up to 523 K. The structure of polyurethane ureas, containing folate derivative of ferrocene, by wide-angle and small angle X-ray method for different content of folate-derivative of ferrocene was investigated. Wide-angle X-ray diffraction data revealed that the introduction of 0.01 mole of folate derivative of ferrocene to the PUU structure leads to the change of period alternating arrangement of flexible and rigid blocks of PUU, significant degradation of heterogeneous structure, but does not cause changes in amorphous structure of the polymer.},
 year = {2017}
}

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TY  - JOUR
T1  - Thermophysical Properties and X-Ray Structure Investigations of Polyurethane Ureas, Containing Folate Derivative of Ferrocene
AU  - Liudmyla Kulyk
AU  - Rita Rozhnova
AU  - Iryna Gladyr
AU  - Nataliia Galatenko
Y1  - 2017/08/15
PY  - 2017
N1  - https://doi.org/10.11648/j.ajpc.20170604.13
DO  - 10.11648/j.ajpc.20170604.13
T2  - American Journal of Physical Chemistry
JF  - American Journal of Physical Chemistry
JO  - American Journal of Physical Chemistry
SP  - 70
EP  - 75
PB  - Science Publishing Group
SN  - 2327-2449
UR  - https://doi.org/10.11648/j.ajpc.20170604.13
AB  - Thermophysical properties of polyurethane ureas by thermogravimetry and differential scanning calorimetry were studied. It was shown, that investigated polyurethane ureas are heat-resistant up to 523 K. The structure of polyurethane ureas, containing folate derivative of ferrocene, by wide-angle and small angle X-ray method for different content of folate-derivative of ferrocene was investigated. Wide-angle X-ray diffraction data revealed that the introduction of 0.01 mole of folate derivative of ferrocene to the PUU structure leads to the change of period alternating arrangement of flexible and rigid blocks of PUU, significant degradation of heterogeneous structure, but does not cause changes in amorphous structure of the polymer.
VL  - 6
IS  - 4
ER  -

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Author Information

Liudmyla Kulyk

Department of Polymers of Medical Appointment, Institute of Macromolecular Chemistry of the National Academy of Sciences of Ukraine, Kyiv, Ukraine
Rita Rozhnova

Department of Polymers of Medical Appointment, Institute of Macromolecular Chemistry of the National Academy of Sciences of Ukraine, Kyiv, Ukraine
Iryna Gladyr

Department of Polymers of Medical Appointment, Institute of Macromolecular Chemistry of the National Academy of Sciences of Ukraine, Kyiv, Ukraine
Nataliia Galatenko

Department of Polymers of Medical Appointment, Institute of Macromolecular Chemistry of the National Academy of Sciences of Ukraine, Kyiv, Ukraine

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APA Style

Liudmyla Kulyk, Rita Rozhnova, Iryna Gladyr, Nataliia Galatenko. (2017). Thermophysical Properties and X-Ray Structure Investigations of Polyurethane Ureas, Containing Folate Derivative of Ferrocene. American Journal of Physical Chemistry, 6(4), 70-75. https://doi.org/10.11648/j.ajpc.20170604.13

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ACS Style

Liudmyla Kulyk; Rita Rozhnova; Iryna Gladyr; Nataliia Galatenko. Thermophysical Properties and X-Ray Structure Investigations of Polyurethane Ureas, Containing Folate Derivative of Ferrocene. Am. J. Phys. Chem. 2017, 6(4), 70-75. doi: 10.11648/j.ajpc.20170604.13

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AMA Style

Liudmyla Kulyk, Rita Rozhnova, Iryna Gladyr, Nataliia Galatenko. Thermophysical Properties and X-Ray Structure Investigations of Polyurethane Ureas, Containing Folate Derivative of Ferrocene. Am J Phys Chem. 2017;6(4):70-75. doi: 10.11648/j.ajpc.20170604.13

Copy | Download

@article{10.11648/j.ajpc.20170604.13,
  author = {Liudmyla Kulyk and Rita Rozhnova and Iryna Gladyr and Nataliia Galatenko},
  title = {Thermophysical Properties and X-Ray Structure Investigations of Polyurethane Ureas, Containing Folate Derivative of Ferrocene},
  journal = {American Journal of Physical Chemistry},
  volume = {6},
  number = {4},
  pages = {70-75},
  doi = {10.11648/j.ajpc.20170604.13},
  url = {https://doi.org/10.11648/j.ajpc.20170604.13},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpc.20170604.13},
  abstract = {Thermophysical properties of polyurethane ureas by thermogravimetry and differential scanning calorimetry were studied. It was shown, that investigated polyurethane ureas are heat-resistant up to 523 K. The structure of polyurethane ureas, containing folate derivative of ferrocene, by wide-angle and small angle X-ray method for different content of folate-derivative of ferrocene was investigated. Wide-angle X-ray diffraction data revealed that the introduction of 0.01 mole of folate derivative of ferrocene to the PUU structure leads to the change of period alternating arrangement of flexible and rigid blocks of PUU, significant degradation of heterogeneous structure, but does not cause changes in amorphous structure of the polymer.},
 year = {2017}
}

Copy | Download

TY  - JOUR
T1  - Thermophysical Properties and X-Ray Structure Investigations of Polyurethane Ureas, Containing Folate Derivative of Ferrocene
AU  - Liudmyla Kulyk
AU  - Rita Rozhnova
AU  - Iryna Gladyr
AU  - Nataliia Galatenko
Y1  - 2017/08/15
PY  - 2017
N1  - https://doi.org/10.11648/j.ajpc.20170604.13
DO  - 10.11648/j.ajpc.20170604.13
T2  - American Journal of Physical Chemistry
JF  - American Journal of Physical Chemistry
JO  - American Journal of Physical Chemistry
SP  - 70
EP  - 75
PB  - Science Publishing Group
SN  - 2327-2449
UR  - https://doi.org/10.11648/j.ajpc.20170604.13
AB  - Thermophysical properties of polyurethane ureas by thermogravimetry and differential scanning calorimetry were studied. It was shown, that investigated polyurethane ureas are heat-resistant up to 523 K. The structure of polyurethane ureas, containing folate derivative of ferrocene, by wide-angle and small angle X-ray method for different content of folate-derivative of ferrocene was investigated. Wide-angle X-ray diffraction data revealed that the introduction of 0.01 mole of folate derivative of ferrocene to the PUU structure leads to the change of period alternating arrangement of flexible and rigid blocks of PUU, significant degradation of heterogeneous structure, but does not cause changes in amorphous structure of the polymer.
VL  - 6
IS  - 4
ER  -

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