Pentadentate N2O3 Schiff Base Complexes of Rare Earth Metals

Khalil Khalaf Abid

doi:doi:10.11648/j.ajac.20130105.12

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Pentadentate N2O3 Schiff Base Complexes of Rare Earth Metals

Khalil Khalaf Abid

Published in American Journal of Applied Chemistry (Volume 1, Issue 5)

Received: 28 October 2013 Published: 10 December 2013

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Abstract

Acyclic Schiff base ligand containing N2O3 donor atoms was synthesized by the reaction of 2,6 – diformyl – 4 – ter-butylphenol and 4 – aminoantipyrine in 1:2 molar ratio. The synthesized ligand (H1L) and Ln(III) complexes [Ln= LaIII, CeIII and GdIII] were characterized by1HN.M.R., 13CN.M.R., mass spectrometry, UV /Visible, FTIR, Elemental analysis (C.H.N.), Magnetic susceptibility and Molar conductivity measurements. A seven coordinated complex obtained through N2O3 and two chloride atoms coordinated to metal ions.

Published in	American Journal of Applied Chemistry (Volume 1, Issue 5)
DOI	10.11648/j.ajac.20130105.12
Page(s)	87-91
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2013. Published by Science Publishing Group

Keywords

Lanthanides, Schiff Bases, 2, 6-Diformyl Phenol, Pentadentate Acyclic Ligand

References

[1]	K. K. Narang, T. R. Raob, S. Sesthab and S. Shrestha; Synth. React. Inorg. Met.- Org.Chem, 30(5), 931(2000).
[2]	Tahaa Z. A., Ajlounia A. M., Al- Hassanb K. A., Hijazi A. K. and Faiqa A. B.; Spectrochimica Acta, Part A 81, 317(2011)
[3]	Singh B. and Singh T. B.; Synth. React. Inorg. Met-Org. Chem., 33, No. 4, 639 (2003)
[4]	A. A. Al-Ameiry; (2012) Res Chem. Intermed. DOI0.1007/s11164-011-0414-8
[5]	K. K. Abid and B. F. Abbas ; (2012) Res Chem Intermed, DOI 10.1007/s11164- 012-0914-1
[6]	Z. H. Abd el-whab; Journal of Coordination Chemistry, 61, No. 20, 3284 (2008).
[7]	A. Hussain and A. R. Chakravarty; J. Chem. Sci., 124, No. 6, 1327 (2012)
[8]	P. Kapoor, R. V. Singh and N. Fahmi; Journal of Coordination Chemistry, 65, No. 2, 262 (2012).
[9]	A. S. Ramasubramanian, B. B. Ramachandra and R. Dileep; Synth. React. Inorg. Met-Org. Nano-Met. Chem., 42, 548 (2012).
[10]	R. C. Palenik, K. A. Abboud, S. P. Summers, L. L. Reitfort and G. J. Palenik; Inorganica Chimica Acta, 359, 4645 (2006).
[11]	T. Arslan, C. O. G. Retiry, M. Tsiouri, J. C. Plakatouras and N. Hadjiliadis; Journal of Coordination Chemistry, 60, No. 6, 699 (2007).
[12]	M. T. Kaczmarek, I. Pospieszna-Markiewicz, M. Kubicki and W. Radecka-Paryzek; Inorg. Chemical Communication, 7, 1247 (2004).
[13]	M. G. B. Drew, M. R. Foreman, M. J. Hudson and K. F. Kennedy; Inorg. Chim. Acta , 57, 4102 (2004).
[14]	P. A. Vigato and S. Tamburin; Coordination Chemical Review, 248, 717(2004).
[15]	C. Benelli and D. Gatteschi; Chemical Review (2002) 102, 2369.
[16]	M. Tsiouri, J. C. Plakatouras, A. Garoufis, V. Nastopoulos and N. Hadjiliadis; Inorganic Chemistry Communications, 5, 844 (2002).
[17]	K. K. Abid and A. B. Omar; (2013) Res. Chem. Intermed., DOI 10.1007/s 11164-013-1306-x
[18]	S. K. Agarwal and J. P. Tandon; Monatsh. Chemistry, 110, 401 (1979).
[19]	B. H. M. Mruthyunjayaswamy, B. Ijare and Y. Jadegoud; J. Braz. Chemical Soc., 16 (4)738 (2005).
[20]	M. S. Annigeri, M. P. Sathisha and V. K. Revankar; Transition Metal Chem., 32, 81 (2007).
[21]	B. Srinivas, N. Arulsamy and P. S. Zacharias; Polyhedron, 10, 731 (1991).
[22]	S. J. Archibald, A. J. Blake, M. Schroder and R. E. P. Winpenny; J. Chemical Soc. Chemical Communication, 1669 (1994).
[23]	T. Szczurek and M. Schlesinger; Rare Earth Spectroscopy" World Scientiﬁc, Singapore, P309 (1985)
[24]	M. H. V. Werts; Science Progress, 88, 101 (2005) .
[25]	N. Greenwood and A. Earnshaw; "Chemistry of the Elements "p1242, 2ndedition, Butterworth –Heinmann (1997).

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Khalil Khalaf Abid. (2013). Pentadentate N2O3 Schiff Base Complexes of Rare Earth Metals. American Journal of Applied Chemistry, 1(5), 87-91. https://doi.org/10.11648/j.ajac.20130105.12

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ACS Style

Khalil Khalaf Abid. Pentadentate N2O3 Schiff Base Complexes of Rare Earth Metals. Am. J. Appl. Chem. 2013, 1(5), 87-91. doi: 10.11648/j.ajac.20130105.12

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AMA Style

Khalil Khalaf Abid. Pentadentate N2O3 Schiff Base Complexes of Rare Earth Metals. Am J Appl Chem. 2013;1(5):87-91. doi: 10.11648/j.ajac.20130105.12

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@article{10.11648/j.ajac.20130105.12,
  author = {Khalil Khalaf Abid},
  title = {Pentadentate N2O3 Schiff Base Complexes of Rare Earth Metals},
  journal = {American Journal of Applied Chemistry},
  volume = {1},
  number = {5},
  pages = {87-91},
  doi = {10.11648/j.ajac.20130105.12},
  url = {https://doi.org/10.11648/j.ajac.20130105.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20130105.12},
  abstract = {Acyclic Schiff base ligand containing N2O3 donor atoms was synthesized by the reaction of 2,6 – diformyl – 4 – ter-butylphenol and 4 – aminoantipyrine in 1:2 molar ratio. The synthesized ligand (H1L) and Ln(III) complexes [Ln= LaIII, CeIII and GdIII] were characterized by1HN.M.R., 13CN.M.R., mass spectrometry, UV /Visible, FTIR, Elemental analysis (C.H.N.), Magnetic susceptibility and Molar conductivity measurements. A seven coordinated complex obtained through N2O3 and two chloride atoms coordinated to metal ions.},
 year = {2013}
}

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TY  - JOUR
T1  - Pentadentate N2O3 Schiff Base Complexes of Rare Earth Metals
AU  - Khalil Khalaf Abid
Y1  - 2013/12/10
PY  - 2013
N1  - https://doi.org/10.11648/j.ajac.20130105.12
DO  - 10.11648/j.ajac.20130105.12
T2  - American Journal of Applied Chemistry
JF  - American Journal of Applied Chemistry
JO  - American Journal of Applied Chemistry
SP  - 87
EP  - 91
PB  - Science Publishing Group
SN  - 2330-8745
UR  - https://doi.org/10.11648/j.ajac.20130105.12
AB  - Acyclic Schiff base ligand containing N2O3 donor atoms was synthesized by the reaction of 2,6 – diformyl – 4 – ter-butylphenol and 4 – aminoantipyrine in 1:2 molar ratio. The synthesized ligand (H1L) and Ln(III) complexes [Ln= LaIII, CeIII and GdIII] were characterized by1HN.M.R., 13CN.M.R., mass spectrometry, UV /Visible, FTIR, Elemental analysis (C.H.N.), Magnetic susceptibility and Molar conductivity measurements. A seven coordinated complex obtained through N2O3 and two chloride atoms coordinated to metal ions.
VL  - 1
IS  - 5
ER  -

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Author Information

Khalil Khalaf Abid

Department of Chemistry, College of Science, Al – Mustansiryah University 10052 Baghdad – Iraq

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APA Style

Khalil Khalaf Abid. (2013). Pentadentate N2O3 Schiff Base Complexes of Rare Earth Metals. American Journal of Applied Chemistry, 1(5), 87-91. https://doi.org/10.11648/j.ajac.20130105.12

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ACS Style

Khalil Khalaf Abid. Pentadentate N2O3 Schiff Base Complexes of Rare Earth Metals. Am. J. Appl. Chem. 2013, 1(5), 87-91. doi: 10.11648/j.ajac.20130105.12

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AMA Style

Khalil Khalaf Abid. Pentadentate N2O3 Schiff Base Complexes of Rare Earth Metals. Am J Appl Chem. 2013;1(5):87-91. doi: 10.11648/j.ajac.20130105.12

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@article{10.11648/j.ajac.20130105.12,
  author = {Khalil Khalaf Abid},
  title = {Pentadentate N2O3 Schiff Base Complexes of Rare Earth Metals},
  journal = {American Journal of Applied Chemistry},
  volume = {1},
  number = {5},
  pages = {87-91},
  doi = {10.11648/j.ajac.20130105.12},
  url = {https://doi.org/10.11648/j.ajac.20130105.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20130105.12},
  abstract = {Acyclic Schiff base ligand containing N2O3 donor atoms was synthesized by the reaction of 2,6 – diformyl – 4 – ter-butylphenol and 4 – aminoantipyrine in 1:2 molar ratio. The synthesized ligand (H1L) and Ln(III) complexes [Ln= LaIII, CeIII and GdIII] were characterized by1HN.M.R., 13CN.M.R., mass spectrometry, UV /Visible, FTIR, Elemental analysis (C.H.N.), Magnetic susceptibility and Molar conductivity measurements. A seven coordinated complex obtained through N2O3 and two chloride atoms coordinated to metal ions.},
 year = {2013}
}

Copy | Download

TY  - JOUR
T1  - Pentadentate N2O3 Schiff Base Complexes of Rare Earth Metals
AU  - Khalil Khalaf Abid
Y1  - 2013/12/10
PY  - 2013
N1  - https://doi.org/10.11648/j.ajac.20130105.12
DO  - 10.11648/j.ajac.20130105.12
T2  - American Journal of Applied Chemistry
JF  - American Journal of Applied Chemistry
JO  - American Journal of Applied Chemistry
SP  - 87
EP  - 91
PB  - Science Publishing Group
SN  - 2330-8745
UR  - https://doi.org/10.11648/j.ajac.20130105.12
AB  - Acyclic Schiff base ligand containing N2O3 donor atoms was synthesized by the reaction of 2,6 – diformyl – 4 – ter-butylphenol and 4 – aminoantipyrine in 1:2 molar ratio. The synthesized ligand (H1L) and Ln(III) complexes [Ln= LaIII, CeIII and GdIII] were characterized by1HN.M.R., 13CN.M.R., mass spectrometry, UV /Visible, FTIR, Elemental analysis (C.H.N.), Magnetic susceptibility and Molar conductivity measurements. A seven coordinated complex obtained through N2O3 and two chloride atoms coordinated to metal ions.
VL  - 1
IS  - 5
ER  -

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